质量水平
方案
98%
表单
liquid
折射率
n20/D 1.463 (lit.)
沸点
59-61 °C/10 mmHg (lit.)
密度
1.919 g/mL at 25 °C (lit.)
SMILES字符串
FC(F)(F)c1cc(I)cc(c1)C(F)(F)F
InChI
1S/C8H3F6I/c9-7(10,11)4-1-5(8(12,13)14)3-6(15)2-4/h1-3H
InChI key
VDPIZIZDKPFXLI-UHFFFAOYSA-N
一般描述
1-Iodo-3,5-bis(trifluoromethyl)benzene is a halogenated hydrocarbon.
应用
1-Iodo-3,5-bis(trifluoromethyl)benzene may be used in the preparation of [bis(trifluoroacetoxy)iodo]perfluoroalkanes. It may be used to investigate the fragmentation reactions of (E)- and (Z)-2-methylbuten-1-yl(aryl)iodonium triflates (aryl = C6H5-, 4-(CF3)C6H4, 3,5-(CF3)2C6H4-).
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
165.2 °F - closed cup
闪点(°C)
74 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Fragmentations of (E)-and (Z)-isomers of 2-methylbuten-1-yl (aryl) iodonium triflates: competing mechanisms for enol triflate formation.
Hinkle RJ.
ARKIVOC (Gainesville, FL, United States), 6, 201-212 (2003)
Aleksandra A Zagulyaeva et al.
The Journal of organic chemistry, 75(6), 2119-2122 (2010-02-19)
[Bis(trifluoroacetoxy)iodo]perfluoroalkanes C(n)F(2n+1)I(OCOCF(3))(2) (n = 4, 6, 8, 10, 12) can be conveniently prepared by the oxidation of the corresponding perfluoroalkyl iodides with Oxone in trifluoroacetic acid at room temperature and subsequently converted to the stable [hydroxy(tosyloxy)iodo]perfluoroalkanes, C(n)F(2n+1)I(OH)OTs, by treatment with
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