374717
2-氟-2-膦酰基乙酸三乙酯
96%
别名:
2-Fluoro-2-phosphonoacetic acid triethyl ester, Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate, Ethyl diethylphosphonofluoroacetate
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线性分子式:
(C2H5O)2P(O)CH(F)CO2C2H5
化学文摘社编号:
分子量:
242.18
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1912161
产品名称
2-氟-2-膦酰基乙酸三乙酯, 96%
InChI
1S/C8H16FO5P/c1-4-12-8(10)7(9)15(11,13-5-2)14-6-3/h7H,4-6H2,1-3H3
SMILES string
CCOC(=O)C(F)P(=O)(OCC)OCC
InChI key
FVPISMANESAJQZ-UHFFFAOYSA-N
assay
96%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.425 (lit.)
bp
75 °C/0.01 mmHg (lit.)
density
1.194 g/mL at 25 °C (lit.)
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Application
Reactant for:
- Diels-Alder reactions
- Biosynthesis of terpene
- Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates
- Synthesis of quinolones
- Horner-Wadsworth-Emmons asymmetric hydration
- Addition reactions and the subsequent application to click chemistry
- Asymmetric intermolecular Stetter reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
P W Collins et al.
Journal of medicinal chemistry, 30(11), 1952-1955 (1987-11-01)
A 4-fluoro analogue of enisoprost was prepared and evaluated for gastric antisecretory and mucosal protective activity in animals. The synthesis centered upon cuprate chemistry but also involved a Wittig reaction to produce a cis fluoro olefinic moiety, a furan rearrangement/isomerization
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