375403
2-甲基-2-咪唑啉
95%
别名:
2-甲基咪唑啉
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关于此项目
经验公式（希尔记法）:
C4H8N2
化学文摘社编号:
分子量:
84.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
208-596-6
MDL number:
Assay:
95%
Form:
solid
InChI key
VWSLLSXLURJCDF-UHFFFAOYSA-N
InChI
1S/C4H8N2/c1-4-5-2-3-6-4/h2-3H2,1H3,(H,5,6)
SMILES string
[H]N1CCN=C1C
assay
95%
form
solid
mp
87 °C (dec.) (lit.)
General description
2-Methyl-2-imidazoline is monomethyl derivative of imidazoline. The self-association of 2-methyl-2-imidazoline was studied in aqueous solution, at different pH values, by ultraviolet spectroscopy.
Kinetics of the reaction of 2-methyl-2-imidazoline with sulfate and hydrogen phosphate radicals has been investigated by flash-photolysis. Rate constant for the reaction was reported to be 108-109M-1s-1.
Application
2-Methyl-2-imidazoline may be used in the synthesis of series of N,N,N′-trisubstituted ethylenediamine derivatives. It may be used in the preparation of 1-alkyl-2-methyl-2-imidazolines, via alkylation with organic halides in the presence of phase transfer catalysis and absence of solvent.
Reactant for:
Synthesis of cyclic-amine-based dithiocarbamate chain transfer agents for RAFT polymerization
Dehydration reactions
Synthesis of push-pull alkenes
Producing organic reductants for transfer hydrogenation
Synthesis of orally available factor Xa inhibitors
Synthesis of cyclic-amine-based dithiocarbamate chain transfer agents for RAFT polymerization
Dehydration reactions
Synthesis of push-pull alkenes
Producing organic reductants for transfer hydrogenation
Synthesis of orally available factor Xa inhibitors
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Self-association of imidazole and its methyl derivatives in aqueous solution. A study by ultraviolet spectroscopy.
Peral F and Gallego E.
Journal of Molecular Structure, 415(1), 187-196 (1997)
A Convenient Synthesis of N, N, N'-Trisubstituted Ethylenediamine Derivatives From 2-Methyl-2-imidazoline.
Xia C, et al.
Synthetic Communications, 30(18), 3307-3315 (2000)
Oxidation of ophthalmic drugs photopromoted by inorganic radicals.
Criado S, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 244, 32-37 (2012)
N-alkylation of 2-methyl-2-imidazolines by phase transfer catalysis without solvent.
Chen X, et al.
Synthetic Communications, 29(17), 3025-3030 (1999)
Organoleptic Characteristics of Flavor Materials
Mosciano, G.
Perfumer & Flavorist, 28, 105-105 (2003)
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