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Merck
CN

375934

Sigma-Aldrich

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide

≥95%, with 1% tert-Butyldimethylchlorosilane

别名:

MTBSTFA+TBDMSCl, 99:1, N-甲基-N-叔丁基二甲基甲硅烷基三氟乙酰胺, MTBSTFA + 1% TBDMSCl, 甲硅烷基化混合物VI

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关于此项目

经验公式(希尔记法):
C9H18F3NOSi
化学文摘社编号:
分子量:
241.33
Beilstein:
3606546
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
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产品名称

N-叔丁基二甲基甲硅烷基-N-甲基三氟乙酰胺,含 1% 叔丁基二甲基氯硅烷, ≥95%

质量水平

方案

≥95%

表单

liquid

包含

1% TBDMSCl

官能团

amine
fluoro

储存温度

−20°C

SMILES字符串

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

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应用

N--丁基二甲基甲硅烷基-N-甲基三氟乙酰胺与1%的 -丁基二甲基氯硅烷通常用于制备N--丁基二甲基甲硅烷基乙醇胺,其是氮芥类物质水解生成的产物。。它还可用于N,O-二酰基羟胺的选择性 O-甲硅烷基化。

象形图

FlameExclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Organometallics, 23, 2157-2161 (2004)
Tsubasa Nakajima et al.
Plant & cell physiology, 55(9), 1605-1612 (2014-06-28)
Cyanobacteria have flexible metabolic capability that enables them to adapt to various environments. To investigate their underlying metabolic regulation mechanisms, we performed an integrated analysis of metabolic flux using transcriptomic and metabolomic data of a cyanobacterium Synechocystis sp. PCC 6803
P Canosa et al.
Journal of chromatography. A, 1072(1), 107-115 (2005-05-11)
A solid-phase microextraction (SPME) method for the determination of triclosan, methyl triclosan, 2,4-dichlorophenol and 2,3,4-trichlorophenol (considered as possible triclosan metabolites) in water samples was optimised. Analytes were first concentrated on a SPME fibre, directly exposed to the sample, and then
Xiaowei Wang et al.
Journal of chromatography. A, 1216(35), 6267-6273 (2009-07-31)
A sample pretreatment method for the determination of 18 chlorophenols (CPs) in aqueous samples by derivatization liquid-phase microextraction (LPME) was investigated using gas chromatography-mass spectrometry. Derivatization reagent was spiked into the extraction solvent to combine derivatization and extraction into one
R Montes et al.
Journal of chromatography. A, 1216(2), 205-210 (2008-12-17)
A fast and novel sample preparation procedure for the determination of triclosan (TCS) and methyltriclosan (MTCS) in water samples is presented. Dispersive liquid-liquid microextraction, using a ternary mixture consisting of a disperser, an extractant and N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA) as derivatization reagent

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Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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