377538
正庚基三苯基溴化磷
97%
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关于此项目
线性分子式:
CH3(CH2)6P(C6H5)3Br
化学文摘社编号:
分子量:
441.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
236-539-5
MDL number:
产品名称
正庚基三苯基溴化磷, 97%
InChI key
WCZSOHSGMBVYFW-UHFFFAOYSA-M
InChI
1S/C25H30P.BrH/c1-2-3-4-5-15-22-26(23-16-9-6-10-17-23,24-18-11-7-12-19-24)25-20-13-8-14-21-25;/h6-14,16-21H,2-5,15,22H2,1H3;1H/q+1;/p-1
SMILES string
[Br-].CCCCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
assay
97%
reaction suitability
reaction type: C-C Bond Formation
mp
173-176 °C (lit.)
functional group
phosphine
Quality Level
Application
Reactant for:
- Stereospecific rearrangement of epoxides to quaternary carbaldehydes
- Synthesis of the male pheromone of two species of termite Zootermopsis
- Regio- and stereoselective TEMPO oxidation
- Diastereoselective synthesis of climacostol for antitumor activity
- Enantioselective synthesis of chiral vinylphosphonate and phosphonate analogs of immunosuppressive agent FTY720
- Preparation of embelin derivatives with XIAP inhibitory and anticancer activity
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Tejia Zhang et al.
Journal of lipid research, 56(8), 1501-1510 (2015-06-11)
Apoptosis is an intricately regulated cellular process that proceeds through different cell type- and signal-dependent pathways. In the mitochondrial apoptotic program, mitochondrial outer membrane permeabilization by BCL-2 proteins leads to the release of apoptogenic factors, caspase activation, and cell death.
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