381020
叔-丁基二氯磷
98%
别名:
叔丁基膦二氯化物
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关于此项目
线性分子式:
(CH3)3CPCl2
化学文摘社编号:
分子量:
158.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
247-386-9
MDL number:
产品名称
叔-丁基二氯磷, 98%
InChI key
NMJASRUOIRRDSX-UHFFFAOYSA-N
InChI
1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3
SMILES string
CC(C)(C)P(Cl)Cl
assay
98%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
mp
44-49 °C (lit.)
functional group
phosphine
Quality Level
Application
叔丁基二氯膦可作为反应物用于合成：
- 二氢苯并氧磷核。
- 叔丁基官能化的1,3-C6H4(CH2PR2)2（PCP）钳形配体。
- 与乙醇钠反应的氯次膦酸盐试剂。
- 2-（叔丁基氢磷酰基）-1-苯基-1H-咪唑衍生物。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Solid-phase synthesis and catalytic screening of polystyrene supported diphosphines.
Samuels MC, et al.
Topics in Catalysis, 59(19-20), 1793-1799 (2016)
Synthesis and coordination chemistry of new asymmetric donor/acceptor pincer ligands, 1, 3-C6H4 (CH2PtBu(Rf))2 (Rf= CF3, C2F5).
Debnath S, et al.
Dalton Transactions, 47(35), 12420-12430 (2018)
Imidazolio-substituted secondary phosphine oxides as potential carbene reagents.
Chang YC, et al.
Polyhedron, 100(19-20), 382-391 (2015)
Synthesis of P-Chiral Dihydrobenzooxaphosphole Core for BI Ligands in Asymmetric Transformations.
Li G, et al.
The Journal of Organic Chemistry, 82(10), 5456-5460 (2017)
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