382094
(R)-(+)-甲基丁二酸二甲酯
99%
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线性分子式:
CH3O2CCH2CH(CH3)CO2CH3
化学文摘社编号:
分子量:
160.17
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1706307
产品名称
(R)-(+)-甲基丁二酸二甲酯, 99%
InChI
1S/C7H12O4/c1-5(7(9)11-3)4-6(8)10-2/h5H,4H2,1-3H3/t5-/m1/s1
SMILES string
COC(=O)C[C@@H](C)C(=O)OC
InChI key
NFOQJNGQQXICBY-RXMQYKEDSA-N
assay
99%
form
liquid
optical activity
[α]20/D +4.8°, c = 2.9 in chloroform
refractive index
n20/D 1.418 (lit.)
bp
80-81 °C/12 mmHg (lit.)
density
1.076 g/mL at 25 °C (lit.)
functional group
ester
Application
Dimethyl (R)-(+)-methylsuccinate can be used in the synthesis of FK-506, a macrolide generally produced by Streptomyces tsukubaensis.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
183.2 °F - closed cup
flash_point_c
84 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Tetrahedron Letters, 31, 3283-3283 (1990)
A chemoenzymatic synthesis of the C10-C19 moiety of FK506
Gu R-L and Sih CJ
Tetrahedron Letters, 31(23), 3283-3286 (1990)
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