389439
1-芘甲醇
98%
别名:
1-羟甲基芘, 1-（1-羟甲基）芘
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关于此项目
经验公式（希尔记法）:
C17H12O
化学文摘社编号:
分子量:
232.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
1-芘甲醇, 98%
InChI
1S/C17H12O/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9,18H,10H2
SMILES string
OCc1ccc2ccc3cccc4ccc1c2c34
InChI key
NGDMLQSGYUCLDC-UHFFFAOYSA-N
assay
98%
form
solid
mp
123-126 °C (lit.)
functional group
hydroxyl
Quality Level
Application
1-芘乙醇可用于：
- 合成腺苷-5′ 的钳形苯桥接荧光选择性传感器-三磷酸盐 (ATP) 检测。
- 作为合成芘端聚甲基丙烯酸缩水甘油酯聚合物的起始原料。
- 作为合成芘核心星形聚合物的引发剂。
- 合成医药和农药领域的重要中间体 1-芘甲醛。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Encapsulation of functional moieties within branched star polymers: effect of chain length and solvent on site isolation.
Hecht S, et al.
Journal of the American Chemical Society, 123(1), 18-25 (2001)
H Glatt et al.
Carcinogenesis, 14(4), 599-602 (1993-04-01)
1-Hydroxymethylpyrene (HMP), a primary benzylic alcohol, and 4H-cyclopenta[def]chrysen-4-ol (OH-CPC), a secondary benzylic alcohol, were investigated for mutagenicity in Salmonella typhimurium (reversion of the his- strain TA98) in the presence of various xenobiotic-metabolizing systems. In the direct test, HMP was inactive
Y J Surh et al.
Carcinogenesis, 11(9), 1451-1460 (1990-09-01)
Our previous studies on 7-hydroxymethyl-12-methylbenz[a]anthracene and 6-hydroxymethylbenzo[a]pyrene showed that cytosolic sulfotransferase activity plays a major role in the formation of hepatic benzylic DNA and RNA adducts by these carcinogens in rats. In the present study, we found similar sulfotransferase activity
H Glatt et al.
Chemico-biological interactions, 92(1-3), 305-319 (1994-06-01)
1-Hydroxymethylpyrene (HMP) is activated to a potent mutagen, detectable in Salmonella typhimurium, in the presence of hepatic cytosol, cofactor for sulfotransferases, and chloride anions. The number of induced mutations is linear to the amount of cytosol used over a wide
Highly efficient oxidation of alcohols to carbonyl compounds in the presence of molecular oxygen using a novel heterogeneous ruthenium catalyst.
Ji H, et al.
Tetrahedron Letters, 43(40), 7179-7183 (2002)
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