399396
安息香
purified by sublimation, ≥99.5%
别名:
α-羟基-α-苯基苯乙酮, 2-羟基-2-苯基苯乙酮, 苯偶姻
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关于此项目
线性分子式:
C6H5CH(OH)COC6H5
化学文摘社编号:
分子量:
212.24
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
204-331-3
Beilstein/REAXYS Number:
391839
MDL number:
产品名称
安息香, purified by sublimation, ≥99.5%
InChI key
ISAOCJYIOMOJEB-UHFFFAOYSA-N
InChI
1S/C14H12O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13,15H
SMILES string
OC(c1ccccc1)C(=O)c2ccccc2
assay
≥99.5%
form
powder
purified by
sublimation
bp
194 °C/12 mmHg (lit.)
mp
134-138 °C (lit.)
Quality Level
Gene Information
human ... ACHE(43), BCHE(590), CES1(1066)
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存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Tsuneomi Kawasaki et al.
Angewandte Chemie (International ed. in English), 50(35), 8131-8133 (2011-07-16)
Trigger happy: chiral oxygen isotopomers of hydrobenzoin ([(18)O](R)-1 and [(18)O](S)-1) acted as chiral triggers to induce the enantioselective addition of iPr(2)Zn to pyrimidine-5-carbaldehyde. An extremely small chiral influence arising from the presence of the oxygen isotope ((18)O) is amplified through
Structures and reactivities of O-methylated Breslow intermediates.
Biplab Maji et al.
Angewandte Chemie (International ed. in English), 51(41), 10408-10412 (2012-09-13)
Javier Izquierdo et al.
Angewandte Chemie (International ed. in English), 51(47), 11686-11698 (2012-10-18)
N-Heterocyclic carbene (NHC) catalyzed transformations have emerged as powerful tactics for the construction of complex molecules. Since Stetter's report in 1975 of the total synthesis of cis-jasmon and dihydrojasmon by using carbene catalysis, the use of NHCs in total synthesis
Qiu-Fen Hu et al.
Journal of natural products, 76(10), 1854-1859 (2013-09-26)
Eight new C-4-alkylated deoxybenzoins (1-8), three new diphenylethylenes (9-11), and five known diphenylethylenes were isolated from Arundina graminifolia. The structures of 1-11 were elucidated by spectroscopic methods including extensive 1D and 2D NMR techniques. Compounds 9-11 are the first naturally
Dah-Yuu Lu et al.
Phytomedicine : international journal of phytotherapy and phytopharmacology, 19(12), 1093-1100 (2012-07-24)
Prenyl-phloroglucinol derivatives from hop plants have been shown to have anticancer activities. This study is the first to investigate the anticancer effects of the new phloroglucinol derivative (2,4-bis(4-fluorophenylacetyl)phloroglucinol; BFP). BFP induced cell death and anti-proliferation in three glioma, U251, U87
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