产品名称
苄基苯基醚, 98%
InChI
1S/C13H12O/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1-10H,11H2
SMILES string
C(Oc1ccccc1)c2ccccc2
InChI key
BOTNYLSAWDQNEX-UHFFFAOYSA-N
assay
98%
bp
286-287 °C (lit.)
mp
39-41 °C (lit.)
functional group
phenoxy
phenyl
General description
苄基苯基醚是一种反应性有机含氧化合物，以醚为官能团，存在于亚烟煤和烟煤中。在氯苯溶液中与溴化铝反应，得到苯酚、o-苄基苯酚和二氯二苯基甲烷的混合物。木质素和煤中的 a-O4 醚键是催化化学中常用的模型化合物。它含有 234 kJ/mol 的弱醚键，属于木质素和低煤级煤中最不耐热的化合物。本文报道了生物质转化过程中常用添加剂碱碳酸盐对过热水中 BPE 反应历程的影响。用铯交换的杂多酸催化苄基苯醚的分解反应。研究了苯基苄醚在不同结晶度的阳离子交换 Y 型分子筛和聚乙烯中的光重排反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Influence of alkali carbonates on benzyl phenyl ether cleavage pathways in superheated water.
Roberts V, et al.
Applied Catalysis. B, Environmental, 95(1), 71-77 (2010)
Catalytic decomposition of benzyl phenyl ether to aromatics over cesium-exchanged heteropolyacid catalyst.
Park HW, et al.
Korean Journal of Chemical Engineering, 28(5), 1177-1180 (2011)
Tibo De Saegher et al.
Materials (Basel, Switzerland), 13(3) (2020-02-09)
Monometallic cerium layered double hydroxides (Ce-LDH) supports were successfully synthesized by a homogeneous alkalization route driven by hexamethylenetetramine (HMT). The formation of the Ce-LDH was confirmed and its structural and compositional properties studied by XRD, SEM, XPS, iodometric analyses and
Understanding the influence of active (zeolite) and passive (polyethylene) reaction cages on photo-Claisen rearrangements of aryl benzyl ethers.
Gu W, et al.
Langmuir, 16(17), 6977-6981 (2000)
Hongliang Wang et al.
ChemSusChem, 11(15), 2562-2568 (2018-07-04)
Hydrodeoxygenation of biorefinery lignin-rich wastes to jet fuel hydrocarbons offers a significant opportunity for enhancing the overall operational efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuels production. However, these wastes usually mainly contain lignin with sugars, furans, and
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