Merck
CN

407607

Sigma-Aldrich

2-羟基苯并噻唑

98%

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别名:
2(3H)-苯并噻唑酮
经验公式(希尔记法):
C7H5NOS
CAS号:
分子量:
151.19
EC 号:
MDL编号:
PubChem化学物质编号:

检测方案

98%

mp

137-140 °C (lit.)

SMILES string

Oc1nc2ccccc2s1

InChI

1S/C7H5NOS/c9-7-8-5-3-1-2-4-6(5)10-7/h1-4H,(H,8,9)

InChI key

YEDUAINPPJYDJZ-UHFFFAOYSA-N

一般描述

2-Hydroxybenzothiazole (2-OHBT) is a 2-substituted benzothiazole. It is a tautomer of 2-benzothiazolinone. Its enthalpy of formation in the gas phase has been determined using high-level ab initio molecular orbital calculations at the G3(MP2)//B3LYP level of theory. Polarized IR spectra of the hydrogen-bonded molecular crystals of 2-OHBT have been studied. Oxidation of 2-OHBT using H2O2/UV and iron(III) photoassisted Fenton techniques have been reported. 2-OHBT is released into wastewaters during the industrial production of 2-mercaptobenzothiazole, a rubber vulcanization accelerator. The anodic oxidation of 2-OHBT on copper, iron and platinum in alcohol and alcohol-water solutions by cyclic polarization and chronoamperometry has been reported.

应用

2-Hydroxybenzothiazole may be employed as carbon, nitrogen and energy supplement in the bacterial cultures. It may be used in the preparation of insulating thin polymer (<0.1μm), via electropolymerization.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Electropolymerization of 2-hydroxybenzothiazole (2-OHBT) in water-methanol media: electrochemical behaviour in NaCl (3%) solution.
Perrin FX, et al.
J. Appl. Electrochem., 27(7), 821-830 (1997)
Structural and energetic characterization of the tautomers 2-benzothiazolinone and 2-hydroxybenzothiazole.
Silva ALR, et al.
Journal of Molecular Structure, 1078, 197-206 (2014)
Influence of molecular electronic properties on the IR spectra of dimeric hydrogen bond systems: polarized spectra of 2-hydroxybenzothiazole and 2-mercaptobenzothiazole crystals.
Flakus HT, et al.
Journal of Molecular Structure, 604(1), 29-44 (2002)
Georgia Gatidou et al.
Chemosphere, 241, 125071-125071 (2019-11-07)
The ready biodegradability of twenty food additives, belonging to the classes of artificial sweeteners, natural sweeteners, preservatives and colorings, was investigated using activated sludge as inoculum and OECD 301F respirometric test. According to the results, saccharin, aspartame, sodium cyclamate, xylitol
Chien-Hao Chen et al.
Food chemistry, 333, 127516-127516 (2020-07-20)
Benzotriazoles (BTRs) and benzothiazoles (BTs) are two groups of emerging concern and high production volume contaminants. Via the biomagnification of the food web, they could jeopardize human health. In this work, rapid determining the presence of five BTRs and two

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