407925
4-氯-3-硝基苯甲酰氯
98%
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关于此项目
线性分子式:
ClC6H3(NO2)COCl
化学文摘社编号:
分子量:
220.01
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
254-133-6
MDL number:
产品名称
4-氯-3-硝基苯甲酰氯, 98%
InChI key
IWLGXPWQZDOMSB-UHFFFAOYSA-N
InChI
1S/C7H3Cl2NO3/c8-5-2-1-4(7(9)11)3-6(5)10(12)13/h1-3H
SMILES string
[O-][N+](=O)c1cc(ccc1Cl)C(Cl)=O
assay
98%
mp
47-54 °C (lit.)
functional group
acyl chloride
chloro
nitro
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Application
4-Chloro-3-nitrobenzoyl chloride may be employed as acylation reagent for the Friedel-Crafts acylation of activated benzenes such as anisole, veratrole and 1,4-dimethoxybenzene. It may be employed for the synthesis of 4-chloro-4-methoxy-3-nitrobenzophenone. It may be employed as acylation reagent for the acylation reaction of the deactivated amines (2- aminopyrimidine, aminopyrazine).
General description
4-Chloro-3-nitrobenzoyl chloride is an acid halide.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Tzvetomira Tzanova et al.
European journal of medicinal chemistry, 44(6), 2724-2730 (2008-10-28)
Considering that oxidative stress is strongly implicated in the toxicity of chemotherapy, much effort is focused on the research of diverse antioxidants as protective agents. An efficient synthesis of three novel benzophenones containing 1,3-thiazol moiety (6a-c) is described. Their antioxidant
Insights into the N,N-diacylation reaction of 2-aminopyrimidines and deactivated anilines: an alternative N-monoacylation reaction.
Theodorou V, et al.
ARKIVOC (Gainesville, FL, United States), 4, 11-23 (2014)
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