409928
N,N -二甲基- o -甲苯胺
99%
别名:
2,N,N-三甲基苯胺, 2-甲基-N,N-二甲基苯胺, N,N,2-三甲基苯胺, N,N-二甲基-2-甲基苯胺, N,N-二甲基-o-甲基苯胺, o-甲基-N,N-二甲基苯胺, o-甲基二甲基苯胺
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关于此项目
线性分子式:
CH3C6H4N(CH3)2
化学文摘社编号:
分子量:
135.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
210-199-8
MDL number:
Assay:
99%
Form:
liquid
产品名称
N,N -二甲基- o -甲苯胺, 99%
Quality Level
InChI key
JDEJGVSZUIJWBM-UHFFFAOYSA-N
InChI
1S/C9H13N/c1-8-6-4-5-7-9(8)10(2)3/h4-7H,1-3H3
SMILES string
CN(C)c1ccccc1C
assay
99%
form
liquid
refractive index
n20/D 1.525 (lit.)
bp
76 °C/18 mmHg (lit.)
density
0.929 g/mL at 25 °C (lit.)
functional group
amine
Application
N,N-二甲基-邻-甲苯胺可用作合成玫瑰黄素的起始试剂。
General description
目前已经评估了N,N-二甲基邻甲苯胺与碘的络合能力。同时研究了四甲基乙二胺对邻-和对-N,N-二甲基-邻-甲苯胺锂化的影响。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Photo-dynamics of roseoflavin and riboflavin in aqueous and organic solvents.
Zirak P, et al.
Chemical Physics, 358(1), 111-122 (2009)
Effect of tetramethylethylenediamine on the metalation of o- and p-N,N-dimethyltoluidines with n-butyllithium. Deuteration and electrophilic condensation of intermediate lithioamines.
Ludt RE, et al.
The Journal of Organic Chemistry, 35(5), 1288-1296 (1970)
Design of Iodonium Salts for UV or Near-UV LEDs for Photoacid Generator and Polymerization Purposes.
Ségolène Villotte et al.
Molecules (Basel, Switzerland), 25(1) (2020-01-08)
Iodonium salts are well established photoacid generators, cationic photoinitiators, as well as additives commonly used in photoredox catalytic cycles. However, as a strong limitation, iodonium salts are characterized by low light absorption properties for λ > 300 nm so that
Molecular Complexes and Their Spectra. X. Molecular Complexes between Iodine and N, N-Dimethylaniline Derivatives.
Tsubomura H.
Journal of the American Chemical Society, 82(1), 40-45 (1960)
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