414883
异氰酸己酯
97%
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关于此项目
线性分子式:
CH3(CH2)5NCO
化学文摘社编号:
分子量:
127.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-763-8
Beilstein/REAXYS Number:
1751836
MDL number:
产品名称
异氰酸己酯, 97%
assay
97%
form
liquid
InChI key
ANJPRQPHZGHVQB-UHFFFAOYSA-N
InChI
1S/C7H13NO/c1-2-3-4-5-6-8-7-9/h2-6H2,1H3
SMILES string
CCCCCCN=C=O
refractive index
n20/D 1.421 (lit.)
bp
162-164 °C (lit.)
density
0.873 g/mL at 25 °C (lit.)
functional group
amine
isocyanate
Quality Level
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Application
异氰酸己酯可用于以下合成：
- 刚性杆状、螺旋异氰酸酯基大分子单体
- 利用活性阴离子聚合制备具有2-乙烯基吡啶的棒-卷-棒三嵌段共聚物
- 通过活性阴离子聚合制备手性聚（n-己基异氰酸酯）（PHIC）大分子单体
General description
异氰酸己酯的抗原性已在半抗原特异性呼吸道超敏反应的豚鼠动物模型中进行了研究。 以稀土三（2,6-二-叔-丁基-4-甲基苯酚酯）[Ln（OAr）3]为引发剂，异氰酸正己酯的聚合反应已有研究。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Resp. Sens. 1 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
138.2 °F - closed cup
flash_point_c
59 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Boer Liu et al.
Molecules (Basel, Switzerland), 26(15) (2021-08-08)
This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit
Pulmonary hypersensitivity to hexyl isocyanate-ovalbumin aerosol in guinea pigs.
M H Karol et al.
Toxicology and applied pharmacology, 51(1), 73-80 (1979-10-01)
Synthesis and Self-Assembly Studies of Amphiphilic Poly (n-hexyl isocyanate)-b lock-poly (2-vinylpyridine)-b lock-poly (n-hexyl isocyanate) Rod-Coil-Rod Triblock Copolymer.
Rahman M, et al.
Macromolecules, 39(15), 5009-5014 (2006)
Maresa Sonnabend et al.
Polymers, 13(12) (2021-07-03)
Due to reasons of sustainability and conservation of resources, polyurethane (PU)-based systems with preferably neutral carbon footprints are in increased focus of research and development. The proper design and development of bio-based polyols are of particular interest since such polyols
Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2, 6-di-tert-butyl-4-methylphenolate).
XU X-Y, et al.
Chemical Research in Chinese Universities, 21(2), 224-226 (2005)
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