415146
原甲酸三异丙酯
97%
别名:
2,2′,2′′-[次甲基三(氧基)]三[丙烷], 2-[二(丙-2-氧基)甲氧基]丙烷, 2-[双(丙-2-氧基)甲氧基]丙烷, 三(2-丙基)原甲酸酯, 三(异丙基)原甲酸酯, 三异丙基原甲酸酯, 正甲酸三异丙酯
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.397 (lit.)
沸点
65-66 °C/18 mmHg (lit.)
密度
0.854 g/mL at 25 °C (lit.)
官能团
ether
SMILES字符串
CC(C)OC(OC(C)C)OC(C)C
InChI
1S/C10H22O3/c1-7(2)11-10(12-8(3)4)13-9(5)6/h7-10H,1-6H3
InChI key
FPIVAWNGRDHRSQ-UHFFFAOYSA-N
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一般描述
原甲酸三异丙酯(TIPO)通过二氯氟甲烷和异丙氧基钾在异丙醇中反应而成。已有报告通过致密碳纳米管(CNT)膜的渗透蒸发技术将TIPO与正己烷分离。
应用
原甲酸三异丙酯可用于制备2-(二异丙氧基甲基)环氧乙烷。
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
107.6 °F - closed cup
闪点(°C)
42 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Miao Yu et al.
Nano letters, 9(1), 225-229 (2008-12-23)
A method is presented to prepare high-density, vertically aligned carbon nanotube (VA-CNT) membranes. The CNT arrays were prepared by chemical vapor deposition (CVD), and the arrays were collapsed into dense membranes by capillary-forces due to solvent evaporation. The average space
Enzymatic Transformations 62. Preparative Scale Synthesis of Enantiopure Glycidyl Acetals using an Aspergillus niger Epoxide Hydrolase-Catalysed Kinetic Resolution.
Doumeche B, et al.
Advanced Synthesis & Catalysis, 348(14), 1948-1957 (2006)
Methylene Derivatives as Intermediates in Polar Reactions. XIX. The Reaction of Potassium Isopropoxide with Chloroform, Bromoform and Dichlorofluoromethane1.
Hine J, et al.
Journal of the American Chemical Society, 82(6), 1398-1401 (1960)
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