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Merck
CN

424013

1-(叔丁氧基羰基)咪唑

97%

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经验公式(希尔记法):
C8H12N2O2
化学文摘社编号:
分子量:
168.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
256-475-1
MDL number:
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产品名称

1-(叔丁氧基羰基)咪唑, 97%

InChI key

MTBKGWHHOBJMHJ-UHFFFAOYSA-N

InChI

1S/C8H12N2O2/c1-8(2,3)12-7(11)10-5-4-9-6-10/h4-6H,1-3H3

SMILES string

CC(C)(C)OC(=O)n1ccnc1

assay

97%

bp

147-150 °C (lit.)

mp

45-47 °C (lit.)

Application

1-(tert-butoxycarbonyl)imidazole was used in the preparation of water soluble polyrotaxane, via modification of α-cyclodextrin in the presence of KOH and N,N′-carbonyldiimidazole.

General description

1-(tert-butoxycarbonyl)imidazole is an imidazole derivative. Its gas-phase elimination kinetics study has been studied both theoretically and experimentally.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

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Joint theoretical and experimental study of the gas-phase elimination kinetics of tert-butyl ester of carbamic, N,N-dimethylcarbamic, N-hydroxycarbamic acids and 1-(tert-butoxycarbonyl)-imidazole.
Mora JR, et al.
Journal of Physical Organic Chemistry, 20(12), 1021-1031 (2007)
Block-Selective Movement of α-Cyclodextrins in Polyrotaxanes of PEI-b-PEG-b-PEI Copolymer.
Choi HS, et al.
Macromolecules, 38(23), 9878-9881 (2005)

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