Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.575 (lit.)
bp
152 °C (lit.)
density
1.436 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
COc1cccc(CBr)c1
InChI
1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
InChI key
ZKSOJQDNSNJIQW-UHFFFAOYSA-N
General description
3-甲氧基苄基溴是一种苄基溴衍生物。
Application
3-甲氧基苄基溴（1-溴甲基-3-甲氧基苯）可用于手性琥珀酸衍生物的邻位二价阴离子的非对映选择性烷基化。
它可用于合成以下物质：
它可用于合成以下物质：
- 6-(3-甲氧基苯基)-己烷-2,4-二酮
- N-(3-甲氧基苄基)-N-(1-甲基-1-苯乙基)-胺
- 2-(3-甲氧基苄基)-3-[(1R)-7,7-二甲基-2-氧代双环[2.2.1]庚-1-基]-(3S)-2-硫代双环[2.2.1]-庚烷四氟硼酸盐
- 1-(3-甲氧基苄基)-5-(1-甲基-1H-咪唑-5-基)-1H-1,2,3-三唑
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Aggarwal VK, et al.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Clayden J, et al.
Tetrahedron, 58(23), 4727-4733 (2002)
Highly diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives: a new general strategy to (R)-?-arylmethyl-?-butyrolactones.
Pohmakotr M, et al.
Tetrahedron Letters, 45(22), 4315-4318 (2004)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 429120-25ML | 04061832105345 |
| 429120-5ML | 04061837008979 |