431966
4-甲酰基苯硼酸
≥95.0%
别名:
4-醛基苯硼酸, 对甲酰苯硼酸
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关于此项目
线性分子式:
HCOC6H4B(OH)2
化学文摘社编号:
分子量:
149.94
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3030770
产品名称
4-甲酰基苯硼酸, ≥95.0%
InChI
1S/C7H7BO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5,10-11H
SMILES string
OB(O)c1ccc(C=O)cc1
InChI key
VXWBQOJISHAKKM-UHFFFAOYSA-N
assay
≥95.0%
mp
237-242 °C (lit.)
functional group
aldehyde
Quality Level
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Application
4-甲酰基苯硼酸是Suzuki交叉偶联反应的底物，用作以下应用的试剂：
- 钯催化的水中Suzuki-Miyaura交叉偶联。
- 芳基硼酸与氟烷基碘的铜介导无配体有氧氟烷基化。
- 硝基芳烃与芳基硼酸的无配体铜催化偶联。
- 三乙胺催化的三组分汉斯酯缩合物。
- 铜催化硝化。
- 毛栓菌催化二烯烃的氧化单裂解。
- 芳基硼酸与羧酸酐或酰氯的钯催化交叉偶联。
- 钯催化氧气氧化交叉偶联反应。
- 敏化剂与作为电子供体的二噻呋烯基单元的合成，用于高效染料敏化太阳能电池。
- 新型抗革兰氏阳性菌蛋白合成抑制剂的合成。
- hexahomotrioxacalix[3]芳烃上边缘的Suzuki芳香偶合反应。
- 铑催化环合作用，将1,5-烯炔转换为环戊烯和螺环戊烯。
Other Notes
含不定量的酸酐
signalword
Warning
hcodes
Hazard Classifications
Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 1
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Suzuki?Miyaura coupling on the three upper rims of hexahomotrioxacalix[3]arenes
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