433047
4-甲基-1-茚酮
97%
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关于此项目
经验公式（希尔记法）:
C10H10O
化学文摘社编号:
分子量:
146.19
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
产品名称
4-甲基-1-茚酮, 97%
InChI
1S/C10H10O/c1-7-3-2-4-9-8(7)5-6-10(9)11/h2-4H,5-6H2,1H3
SMILES string
Cc1cccc2C(=O)CCc12
InChI key
RUORWXQKVXTQJJ-UHFFFAOYSA-N
assay
97%
form
solid
mp
94-96 °C (lit.)
functional group
ketone
Application
4-Methyl-1-indanone may be used for the following syntheses:
- 3,6-dimethylcholanthrene
- 3,6-dimethyl-7-methoxycholanthrene
- 3-methyl-7-methoxycholanthrene
- methyl 4-methyl-1-fluoroindan-1-carboxylate (4-Me-FICA Me ester)
General description
4-Methyl-1-indanone on condensation with 2-lithio-N,N-diethyl-1-napthamide and 2-lithio-N,N-diethyl-8-methoxy-1-napthamide, followed by hydrolysis afforded 2-(1-hydroxy-4-methylindan-1-yl)-1-naphthoic acid lactone and 2-(1-hydroxy-4-methylindan-1-yl)-8-methoxy-1-naphthoic acid lactone respectively.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Syntheses of 3, 6-dimethylcholanthrene, 3, 6-dimethyl-7-methoxycholanthrene and 3-methyl-7-methoxycholanthrene.
Newman MS and Sujeeth PK.
The Journal of Organic Chemistry, 49(16), 2841-2843 (1984)
Jyunichi Koyanagi et al.
Chemical & pharmaceutical bulletin, 62(8), 816-819 (2014-06-13)
An improved synthetic route has been developed for the preparation of methyl 1-fluoroindan-1-carboxylate (FICA Me ester) from 1-indanone. Methyl 4-methyl-1-fluoroindan-1-carboxylate (4-Me-FICA Me ester) was also prepared following the same procedure.
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