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线性分子式:
C6H4[Si(CH3)3]2
化学文摘社编号:
分子量:
222.47
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1867055
Assay:
96%
Form:
solid
产品名称
1,4-双(三甲基甲硅烷基)苯, 96%
InChI
1S/C12H22Si2/c1-13(2,3)11-7-9-12(10-8-11)14(4,5)6/h7-10H,1-6H3
SMILES string
C[Si](C)(C)c1ccc(cc1)[Si](C)(C)C
InChI key
NVRBTKMAZQNKPX-UHFFFAOYSA-N
assay
96%
form
solid
bp
194 °C/742 mmHg (lit.)
mp
91-94 °C (lit.)
Quality Level
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Application
1,4-双(三甲基硅烷基)苯 (TMSB) 可用于:
- 作为前体通过等离子体辅助化学气相沉积(CVD)工艺开发碳化硅涂层
- 作为定量核磁共振波谱法 (qNMR) 中的二级标准品
- 作为1H NMR波谱法定量测定DMSO-d6溶液中有机小分子的内标物。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
347.0 °F - closed cup
flash_point_c
175 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Use and qualification of primary and secondary standards employed in quantitative 1H NMR spectroscopy of pharmaceuticals
Rundlof T, et al.
Journal of Pharmaceutical and Biomedical Analysis, 93(11), 111-117 (2014)
Role of vapor pressure of 1, 4-bis (trimethylsilyl) benzene in developing silicon carbide thin film using a plasma-assisted liquid injection chemical vapor deposition process
Selvakumar J, et al.
Surface and Coatings Technology, 205(11), 3493-3498 (2011)
Characterization of small combinatorial chemistry libraries by 1H NMR. Quantitation with a convenient and novel internal standard
Pinciroli V, et al.
Journal of Combinatorial Chemistry, 3(5), 434-440 (2001)
Synthesis of 1, 4-dihydropyrrolo [3, 2-b] pyrrole.
Kumagai T, et al.
Tetrahedron Letters, 25(49), 5669-5672 (1984)
Torgny Rundlöf et al.
Journal of pharmaceutical and biomedical analysis, 93, 111-117 (2013-11-12)
Standards are required in quantitative NMR (qNMR) to obtain accurate and precise results. In this study acetanilide was established and used as a primary standard. Six other chemicals were selected as secondary standards: 3,4,5-trichloropyridine, dimethylterephthalate, maleic acid, 3-sulfolene, 1,4-bis(trimethylsilyl)benzene, and
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