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Merck
CN

454338

二聚环戊二烯

contains BHT as stabilizer

别名:

4,7-亚甲基-3a,4,7,7a-四氢茚, DCPD, 环戊二烯二聚体

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关于此项目

经验公式（希尔记法）:
C10H12
化学文摘社编号:
77-73-6
分子量:
132.20
Beilstein:
1904092
EC 号:
201-052-9
MDL编号:
MFCD00078246
UNSPSC代码:
12352100
PubChem化学物质编号:
24868570
NACRES:
NA.22

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方案

≥96.0%

质量水平

200

表单

liquid

包含

BHT as stabilizer

沸点

170 °C ((lit.))
170 °C (lit.)

mp

33 °C ((lit.))
33 °C (lit.)

溶解性

water: slightly soluble 0.02 g/L at 25 °C

密度

0.986 g/mL at 25 °C ((lit.))
0.986 g/mL at 25 °C (lit.)

SMILES字符串

C1C=CC2C3CC(C=C3)C12

InChI

[1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1]
1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1

InChI key

[HECLRDQVFMWTQS-AFWXGSBKSA-N]
HECLRDQVFMWTQS-AFWXGSBKSA-N

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相关类别

一般描述

双环戊二烯（DCPD）是环戊二烯的二聚体，由两个不饱和双键组成（一个在降冰片烯环上，一个在环戊烯环上）。DCPT 可单独用于聚合物中，也可与其他碳氢化合物一起使用。它也用于制药、弹性体、聚碳酸酯和聚酯树脂。

应用

双环戊二烯可用于：
  • 采用 VARTM（真空辅助树脂转移模塑）工艺制备 CF/p-DCPD（碳纤维/聚双环戊二烯）复合材料。
  • 在 η5-环戊二烯基三（二甲基氨基）锆催化剂的制备中。
  • 在纤维素–马来酸酐–双环戊二烯共聚物基体的自由基聚合合成中。

特点和优势

DCPD 与邻苯二甲酸和间苯二甲酸聚酯相比具有以下优点：
  • 低收缩率
  • 降低成本效益
  • 减少苯乙烯的排放
  • 薄层快速固化

警示用语：

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

89.6 °F - closed cup

闪点(°C)

32 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX9553
MKCR6199
MKCR2443
0000073517
0000073646

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Sebastijan Kovačič et al.
ACS applied materials & interfaces, 6(21), 19075-19081 (2014-10-22)
Zinc(II) oxide nanoparticles were used for the stabilization of dicyclopentadiene (DCPD)-water-based high internal phase emulsions (HIPEs), which were subsequently cured using ring-opening metathesis polymerization (ROMP). The morphology of the resulting ZnO-pDCPD nanocomposite foams was investigated in correlation to the nanoparticle
Frontal ring-opening metathesis polymerization of dicyclopentadiene.
Mariani A, et al.
Macromolecules, 34(19), 6539-6541 (2001)
Anna Kozłowska et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 20(43), 14120-14125 (2014-09-11)
Cyclic Ru-phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne and cross-metathesis (CM) reactions, including butenolysis, with
Morphological and mechanical evaluation of hybrid organic-inorganic thermoset copolymers of dicyclopentadiene and mono-or tris (norbornenyl)-substituted polyhedral oligomeric silsesquioxanes.
Constable GS, et al.
Macromolecules, 37(4), 1276-1282 (2004)
Andre H St Amant et al.
Journal of the American Chemical Society, 141(34), 13619-13624 (2019-08-08)
Herein, we report the development of a scalable and synthetically robust building block based on norbornadiene (NBD) that can be broadly incorporated into a variety of macromolecular architectures using traditional living polymerization techniques. By taking advantage of a selective and
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