Merck
CN
所有图片(1)

文件

459852

Sigma-Aldrich

蒽-9,10-二腈

97%

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别名:
9,10-二氰基蒽
经验公式（希尔记法）:
C16H8N2
CAS号:
1217-45-4
分子量:
228.25
Beilstein:
1646384
MDL编号:
MFCD00041733
PubChem化学物质编号:
24869608
NACRES:
NA.22

检测方案

97%

mp

340 °C (lit.)

SMILES string

N#Cc1c2ccccc2c(C#N)c3ccccc13

InChI

1S/C16H8N2/c17-9-15-11-5-1-2-6-12(11)16(10-18)14-8-4-3-7-13(14)15/h1-8H

InChI key

BIOPPFDHKHWJIA-UHFFFAOYSA-N

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一般描述

9,10-Anthracenedicarbonitrile (DCA, ADC) is an anthracene derivative. Photochemical reactions of DCA in MeCN-MeOH or MeCN-H2O containing hydroxides or methoxides affords 9-methylimino-10-anthracenecarbonitrile. It participates in the generation of nucleophilic α-hydroxymethyl radicals from α-silyl ethers by irradiation. Binding energy of 9,10-anthracenedicarbonitrile adsorbed onto graphene is -1.23eV.

应用

9,10-Anthracenedicarbonitrile may be used as photosensitizer to investigate the photoisomerization of trans-stilbene (TS) in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H2O system.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids.
Boning W, et al.
The Journal of Physical Chemistry B, 119, 14790-14799 (2015)
a-Silyl Ethers as Hydroxymethyl Anion Equivalents in Photoinduced Radical Electron Transfer Additions.
Gutenberger G, et al.
Angewandte Chemie (International Edition in English), 37(5), 660-662 (1998)
Xia Guo et al.
Journal of colloid and interface science, 283(2), 578-584 (2005-02-22)
Photoisomerization of trans-stilbene (TS) was investigated in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H(2)O systems in order to establish the relationship between the reaction yields and the compositions and structures of molecular organized assemblies. The results show that, in SDS/BA/H(2)O systems
Steven Bailey et al.
The Journal of chemical physics, 140(5), 054708-054708 (2014-02-12)
To identify families of stable planar anchor groups for use in single molecule electronics, we report detailed results for the binding energies of two families of anthracene and pyrene derivatives adsorbed onto graphene. We find that all the selected derivatives
The photochemical reactions of 9, 10-anthracenedicarbonitrile and 1, 4-naphthalenedicarbonitrile in acetonitrile in the presence of bases.
Freccero M, et al.
Tetrahedron, 50(7), 2115-2130 (1994)
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