463469
2-氨基-3,5-二溴苯甲醛
97%
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关于此项目
线性分子式:
H2NC6H2(Br)2CHO
化学文摘社编号:
分子量:
278.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
256-841-0
MDL number:
产品名称
2-氨基-3,5-二溴苯甲醛, 97%
InChI key
RCPAZWISSAVDEA-UHFFFAOYSA-N
InChI
1S/C7H5Br2NO/c8-5-1-4(3-11)7(10)6(9)2-5/h1-3H,10H2
SMILES string
Nc1c(Br)cc(Br)cc1C=O
assay
97%
mp
130-135 °C (lit.)
functional group
aldehyde
bromo
Quality Level
Application
2-Amino-3,5-dibromobenzaldehyde may be employed in the preparation of tetradentate Schiff base ligands, via condensation with aliphatic diamines. These ligands forms nickel (II) and oxovanadium(IV) complexes.
General description
2-Amino-3,5-dibromobenzaldehyde has been identified as one of the oxidation product of bromhexine by controlled potential electrolysis followed by HPLC-UV and GC-MS. It participates in the Friedländer condensation of C-β−glycosylic ketones to form 2-substituted quinoline derivatives.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
M Turchán et al.
Talanta, 73(5), 913-919 (2007-10-31)
A complete electrochemical study and a novel electroanalytical procedure for bromhexine quantitation are described. Bromhexine in methanol/0.1molL(-1) Britton-Robinson buffer solution (2.5/97.5) shows an anodic response on glassy carbon electrode between pH 2 and 7.5. By DPV and CV, both peak
Khosro Mohammadi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 146, 221-227 (2015-03-31)
The tetradentate Schiff base ligands (L(1)-L(4)), were synthesized by reaction between 2-amino-3,5-dibromobenzaldehyde and aliphatic diamines. Then, nickel and oxovanadium(IV) complexes of these ligands were synthesized and characterized by (1)H NMR, Mass, IR, UV-Vis spectroscopy and thermogravimetry. The kinetic parameters of
Subbiah Nagarajan et al.
Carbohydrate research, 345(14), 1988-1997 (2010-08-07)
Regioselective facile one-pot synthesis of 16 different sugar-based quinoline, naphthyridine, and xanthone derivatives is reported. The compounds are characterized by NMR spectroscopy and elemental analysis. The beta-Anomeric form of the sugar moiety was identified from (1)H NMR studies. Antimicrobial studies
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