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464864

6,6′-二溴-1,1′-二-2-萘酚

Name: 6,6′-二溴-1,1′-二-2-萘酚
Brand: ALDRICH

97%

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关于此项目

线性分子式:

[C₁₀H₅(Br)OH]₂

化学文摘社编号:

13185-00-7

分子量:

444.12

UNSPSC Code:

12352100

PubChem Substance ID:

24870227

MDL number:

MFCD00798290

Assay:

97%

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属性

assay

97%

mp

204-206 °C (lit.)

SMILES string

Oc1ccc2cc(Br)ccc2c1-c3c(O)ccc4cc(Br)ccc34

InChI

1S/C20H12Br2O2/c21-13-3-5-15-11(9-13)1-7-17(23)19(15)20-16-6-4-14(22)10-12(16)2-8-18(20)24/h1-10,23-24H

InChI key

OORIFUHRGQKYEV-UHFFFAOYSA-N

说明

General description

6,6′-Dibromo-1,1′-bi-2-naphthol is a 1,1′-bi-2-naphthol derivative. Vibrational circular dichroism (VCD), electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra for the enantiomers of 6,6′-dibromo-1,1′-bi-2-naphthol have been evaluated.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

16122TC

00117TC

00216DR

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Diastereoselective and enantioselective glyoxylate-ene reaction catalyzed by new class of binaphthol-derived titanium complex.

Terada M, et al.

Tetrahedron Letters, 35(36), 6693-6696 (1996)

Conformational sensitivity of chiroptical spectroscopic methods: 6,6'-dibromo-1,1'-bi-2-naphthol.

Prasad L Polavarapu et al.

The journal of physical chemistry. A, 113(18), 5423-5431 (2009-04-16)

The experimental vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotatory dispersion (ORD) spectra for both enantiomers of 6,6'-dibromo-1,1'-bi-2-naphthol have been measured. The corresponding quantum chemical predictions for three different orientations of hydroxyl groups in this molecule were

Novel binuclear chiral zirconium catalysts used in enantioselective strecker reactions.

S Kobayashi et al.

Chirality, 12(5-6), 540-543 (2000-05-29)

A novel binuclear chiral zirconium catalyst was successfully used in enantioselective Strecker reactions. The catalyst was readily prepared from zirconium t-butoxide (Zr(OtBu)4), (R)-6,6'-dibromo-1, 1'-bi-2-naphthol ((R)-6-Br-BINOL), and (R)-3,3'-dibromo-1, 1'-bi-2-naphthol ((R)-3-Br-BINOL) to form unique binuclear structure. It was revealed that a combination

全球贸易项目编号

货号	GTIN
464864-1G	04061825856490