468460
1,4-二甲氧基萘
97%
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关于此项目
经验公式（希尔记法）:
C12H12O2
化学文摘社编号:
分子量:
188.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
233-209-2
MDL number:
产品名称
1,4-二甲氧基萘, 97%
assay
97%
InChI key
FWWRTYBQQDXLDD-UHFFFAOYSA-N
InChI
1S/C12H12O2/c1-13-11-7-8-12(14-2)10-6-4-3-5-9(10)11/h3-8H,1-2H3
SMILES string
COc1ccc(OC)c2ccccc12
mp
86-90 °C (lit.)
Application
1,4-Dimethoxynaphthalene may be used in the preparation of 1,7-dideoxy-3-demethylprekinamycin and 3-acetoxy-2-bromo-1,4-dimethoxynaphthalene.3-acetoxy-2-bromo-1,4-dimethoxynaphthalene
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
William Williams et al.
The Journal of organic chemistry, 62(13), 4364-4369 (1997-06-27)
2-(Diazobenzyl)-p-naphthoquinone was synthesized from 2-benzyl-1,4-dimethoxynaphthalene by cerric ammonium nitrate oxidation to 2-benzyl-p-naphthoquinone followed by diazo transfer with tosyl azide. 1,7-Dideoxy-3-demethylprekinamycin was prepared from 1,4-dimethoxynaphthalene by bromination, lithiation, and condensation with acetanthranil to give 2-(2'-N-acetaminobenzoyl)-1,4-dimethoxynaphthalene, which, following deacylation, was subjected to
Novel haloacetoxylation of 1, 4-dimethoxynaphthalenes using hypervalent iodine chemistry.
Evans PA and Brandt TA.
Tetrahedron Letters, 27(36), 6443-6446 (1996)
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