470813
3-乙酰苯基硼酸
≥95%
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About This Item
线性分子式:
CH3COC6H4B(OH)2
CAS Number:
分子量:
163.97
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥95%
杂质
<10% 3-acetylphenylboronic anhydride
mp
204-208 °C (lit.)
官能团
ketone
SMILES字符串
CC(=O)c1cccc(c1)B(O)O
InChI
1S/C8H9BO3/c1-6(10)7-3-2-4-8(5-7)9(11)12/h2-5,11-12H,1H3
InChI key
SJGGDZCTGBKBCK-UHFFFAOYSA-N
应用
3-Acetylphenylboronic acid can be used as a substrate:
- In the synthesis of symmetric biaryls via oxidative dimerization using a palladium catalyst and water as a solvent.
- In the synthesis of aryl fluorides through electrophilic fluorination reaction using acetyl hypofluorite.
- In the coupling reactions of organoboranes with olefins using molecular oxygen and palladium catalyst.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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