产品名称
4-溴苄胺, 96%
InChI key
XRNVSPDQTPVECU-UHFFFAOYSA-N
InChI
1S/C7H8BrN/c8-7-3-1-6(5-9)2-4-7/h1-4H,5,9H2
SMILES string
NCc1ccc(Br)cc1
assay
96%
bp
110-112 °C/30 mmHg (lit.)
mp
25 °C (lit.)
density
1.473 g/mL at 25 °C (lit.)
functional group
amine
bromo
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Application
4-溴苄胺(p-溴苄胺)可用于合成7-[(p-溴苄基)脲基]-7,8-二氢-α-双丁二烯。
它可用于合成以下4-联苯甲胺衍生物:
它可用于合成以下4-联苯甲胺衍生物:
- (4′-氟-4-联苯)甲胺
- (4′-甲氧基-4-联苯)甲胺
- (2′-甲氧基-4-联苯)甲胺
- (3′-氰基-4-联苯)甲胺
General description
4-溴苄胺(BBA)又名 p-溴苄胺,是一种芳基溴化物。据报道,在存在红铜的条件下,其可由BBA选择性地形成腈或亚胺。 BBA形成2,6,9-三氮杂双环[3.3.1]壬烷衍生物的formal[4 + 4]反应已有研究。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Silvia Galiano et al.
Bioorganic & medicinal chemistry, 15(11), 3896-3911 (2007-04-05)
We have designed and synthesized two novel series of MCH-R1 antagonists based on a substituted biphenylmethyl urea core. SAR was explored, suggesting that optimal binding with the receptor was achieved when the biphenylmethyl group and the linker were substituted on
Jiaqing Wang et al.
Chemical communications (Cambridge, England), 50(42), 5637-5640 (2014-04-16)
A novel, efficient, convenient and environmentally friendly approach for the synthesis of nitriles and imines from primary amines has been developed. Using commercially available red copper as the catalyst, ammonium bromide as the co-catalyst and molecular oxygen as the sole
Jing Zhuang et al.
Nanoscale, 11(31), 14553-14560 (2019-07-26)
An all-inorganic CsPbI2Br perovskite with excellent phase stability and thermal stability has been considered to be a promising candidate for photovoltaic application. However, low efficiency and high moisture sensitivity hinder its advancement. In this work, we exploit 4-bromobenzylamine hydriodate post-treatment
Efficient synthesis of 2,6,9-triazabicyclo [3.3.1] nonanes through amine-mediated formal [4+4] reaction of unsaturated imines.
Tanaka K, et al.
Tetrahedron Letters, 53(44), 5899-5902 (2012)
Nitrogenous bisabolene sesquiterpenes from marine invertebrates.
Gulavita NK, et al.
The Journal of Organic Chemistry, 51(26), 5136-5139 (1986)
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