481947
膦酰氯三聚体
99.95% trace metals basis
别名:
六氯三聚磷腈, 六氯环三聚膦腈, 膦酰氯三聚体
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关于此项目
线性分子式:
(NPCl2)3
化学文摘社编号:
分子量:
347.66
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
EC Number:
213-376-8
MDL number:
产品名称
膦酰氯三聚体, 99.95% trace metals basis
InChI key
UBIJTWDKTYCPMQ-UHFFFAOYSA-N
InChI
1S/Cl6N3P3/c1-10(2)7-11(3,4)9-12(5,6)8-10
SMILES string
Clp1(Cl)np(Cl)(Cl)np(Cl)(Cl)n1
assay
99.95% trace metals basis
mp
112-115 °C (lit.)
density
1.98 g/mL at 25 °C (lit.)
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Application
用于合成"蒲公英"（球状）树枝状聚合物的试剂。开环聚合、用于过渡金属的配位体和/或配位体前体以及研究 P-Cl 键取代反应都是该产品倍受关注的应用。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Ji-Yeon Seong et al.
International journal of pharmaceutics, 314(1), 90-96 (2006-03-22)
Biocompatible and thermosensitive poly(organophosphazenes) with a lower critical solution temperature (LCST) below body temperature have been designed with the aim for the local delivery of peptide and protein drugs. These polymers could be synthesized by introducing short chain tri- or
David K Y Lee et al.
Dalton transactions (Cambridge, England : 2003), 39(22), 5341-5348 (2010-05-05)
Two novel cyclic phosphazenes with asymmetric spiro rings were synthesized via reactions of hexachlorocyclotriphosphazene with chiral amino alcohol residues. The reactions showed preferential formation of the cis isomer possibly due to the delocalization of the lone pair electrons of the
Studies on the reaction of hexachlorocyclotriphosphazene and 2-hydroxyethyl methacrylate and on the physical properties of its polymer.
M Anzai et al.
The Journal of Nihon University School of Dentistry, 26(2), 109-118 (1984-06-01)
Tam T T Bui et al.
Chirality, 17(8), 438-443 (2005-08-13)
The gem-disubstituted cyclotriphosphazene 1 reacted with piperazine (pip) to give the piperazine-bridged derivative 2, which is expected to exist in meso and racemic forms because the two PCl (pip) groups are stereogenic. The proton-decoupled (31)P NMR spectrum of 2 gave
Hiroyoshi Kawakami et al.
Artificial organs, 26(10), 883-890 (2002-09-26)
We investigated biodegradation and biocompatibility of poly(organophosphazenes). We prepared poly(organophosphazenes) having different side chain groups. The blood compatibility of poly(organophosphazenes) containing fluorinated side groups, poly(bis[trifluoroethoxy]phosphazene) (PbFP) and poly([trifluoroethoxy][ethyl glycinate]phosphazene) (PFGP), without heparinization were evaluated in vitro. The deformation and aggregation
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