496065
2,6-双[(4R)-4-苯基-2-噁唑啉基]吡啶
98%
别名:
(R,R)-2,6-双(4,5-二氢-4-苯基-2-噁唑基)吡啶, (R,R)-2,6-双(4-苯基-2-噁唑啉基)吡啶
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关于此项目
经验公式（希尔记法）:
C23H19N3O2
化学文摘社编号:
分子量:
369.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
2,6-双[(4R)-4-苯基-2-噁唑啉基]吡啶, 98%
InChI
1S/C23H19N3O2/c1-3-8-16(9-4-1)20-14-27-22(25-20)18-12-7-13-19(24-18)23-26-21(15-28-23)17-10-5-2-6-11-17/h1-13,20-21H,14-15H2/t20-,21-/m0/s1
SMILES string
C1OC(=N[C@@H]1c2ccccc2)c3cccc(n3)C4=N[C@@H](CO4)c5ccccc5
InChI key
HLHBIMJNCKZZQO-SFTDATJTSA-N
assay
98%
optical activity
[α]22/D 187°, c = 1 in methylene chloride
mp
171-175 °C (lit.)
functional group
ether
phenyl
Quality Level
Application
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine [Pybox] may be used as a chiral ligand in the copper-catalyzed enatioselective arylation of N-arylated tetrahydroisoquinolines (THIQs) with arylboronic acids in the presence of a photoredox catalyst.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Copper-catalyzed asymmetric sp3 C-H arylation of tetrahydroisoquinoline mediated by a visible light photoredox catalyst.
Querard P, et al.
Beilstein Journal of Organic Chemistry, 12(1), 2636-2643 (2016)
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