516139
4-氯-2-碘苯胺
98%
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关于此项目
线性分子式:
ClC6H3(I)NH2
化学文摘社编号:
分子量:
253.47
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
263-839-3
MDL number:
产品名称
4-氯-2-碘苯胺, 98%
InChI key
FLEJOBRWKBPUOX-UHFFFAOYSA-N
InChI
1S/C6H5ClIN/c7-4-1-2-6(9)5(8)3-4/h1-3H,9H2
SMILES string
Nc1ccc(Cl)cc1I
assay
98%
mp
39-43 °C (lit.)
functional group
chloro
iodo
Quality Level
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
>228.2 °F - closed cup
flash_point_c
> 109 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Regioselective iodination of aryl amines using 1, 4-dibenzyl-1, 4-diazoniabicyclo [2.2. 2] octane dichloroiodate in solution and under solvent-free conditions.
Alikarami M, et al.
Bulletin of the Chemical Society of Ethiopia, 29(1), 157-162 (2015)
Quinazolines. VI. Synthesis of 2,4-diaminoquinazolines from anthranilonitriles.
A Rosowsky et al.
Journal of medicinal chemistry, 13(5), 882-886 (1970-09-01)
Wing S Cheung et al.
The Journal of organic chemistry, 70(9), 3741-3744 (2005-04-23)
[reaction: see text] An efficient and versatile method for stereoselective synthesis of (E)-3,3-(diarylmethylene)indolinones by a palladium-catalyzed tandem Heck-carbocyclization/Suzuki-coupling sequence is presented. Factors influencing yield and selectivity, namely catalyst, coordinating ligand, and solvent, are detailed.
Stereoselective Synthesis of (E)-3-(Methoxycarbonyl) methylene-1, 3-dihydroindol-2-ones by Palladium-Catalyzed Oxidative Carbonylation of 2-Ethynylanilines.
Gabriele B, et al.
European Journal of Organic Chemistry, 24, 4607-4613 (2001)
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