Merck
CN

529621

Sigma-Aldrich

双(三苯基膦)氯化镍(II)

99.99% trace metals basis

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别名:
NiCl2(PPh3)2, 二氯化双(三苯基膦基)镍(II), 双(三苯基膦)二氯化镍(II)
线性分子式:
[(C6H5)3P]2NiCl2
CAS号:
分子量:
654.17
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

检测方案

99.99% trace metals basis

形式

powder or crystals

reaction suitability

core: nickel

mp

250 °C (dec.) (lit.)

SMILES string

Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

ZBRJXVVKPBZPAN-UHFFFAOYSA-L

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应用

Ni(PPh3)2Cl2 可被用于利用氯二苯基膦进行镍辅助的联芳基O,N三氟甲磺酸磷化。

象形图

Exclamation markHealth hazard

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1

储存分类代码

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

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  5. What are some uses for Bis(triphenylphosphine)nickel(II) dichloride, product 529621?

    Bis(triphenylphosphine)nickel(II) dichloride can be used for the following:1. Precatalyst for the nickel-catalyzed substitution of allylic carbonates with aryl and alkenyl borates.2. Efficient catalyst for the Suzuki coupling of aryl chlorides.3. Catalyst for the three-component synthesis of 1,4-dienes from allenes, vinyl/aryl iodides and alkenylzirconium reagents.4. Catalyst for the β-selective hydroalumination of terminal alkynes.5. Catalyst for the C-P cross-coupling reaction of arylnitriles.

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Chelating Retardation Effect in Nickel Assisted Phosphination: Syntheses of Atropisomeric P,N Ligands
Kwong FY, et al.
Tetrahedron, 56(45), 8893-8899 (2000)

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