533262
2-氟-6-甲基吡啶
97%
别名:
6-氟-2-甲基吡啶
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关于此项目
经验公式（希尔记法）:
C6H6FN
化学文摘社编号:
分子量:
111.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-980-8
MDL number:
产品名称
2-氟-6-甲基吡啶, 97%
InChI key
UDMNVTJFUISBFD-UHFFFAOYSA-N
InChI
1S/C6H6FN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3
SMILES string
Cc1cccc(F)n1
assay
97%
refractive index
n20/D 1.47 (lit.)
bp
140-141 °C (lit.)
density
1.077 g/mL at 25 °C (lit.)
Application
2-Fluoro-6-methylpyridine may be used in the preparation of:
- 2-fluoro-6-pyridinecarboxylic acid
- 2,2′-[1-(6-methylpyridin-2-yl)ethane-1,1-diyl]dipyridine
- 2-fluoropyridine-6-aldoxime
- 2-fluoro-6-(dibromomethyl)pyridine
General description
2-Fluoro-6-methylpyridine, also known as 2-fluoro-6-picoline, can be prepared via diazotization of 2-amino-6-methylpyridine in hydrogen fluoride containing 40% pyridine solution. The effect of substituents on spectral properties of 2-fluoro-6-methylpyridine has been investigated based on 13C NMR, UV and IR spectral data.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
152.1 °F - closed cup
flash_point_c
66.7 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Efficient synthesis of pentakis-and tris (pyridine) ligands.
Unal EA, et al.
Tetrahedron Letters, 53(1), 54-55 (2012)
Separation of Geometric Isomers of a Dicopper Complex by Using a 19F-Labeled Ligand: Dynamics, Structures, and DFT Calculations.
Durot S, et al.
Inorganic Chemistry, 49(17), 7832-7840 (2010)
A facile preparation of fluoropyridines from aminopyridines via diazotization and fluorodediazoniation in HF or HF-pyridine solutions.
Fukuhara T, et al.
Journal of Fluorine Chemistry, 38(3), 435-438 (1988)
Synthesis of some fluorine-containing pyridinealdoximes of potential use for the treatment of organophosphorus nerve-agent poisoning.
Timperley CM, et al.
Journal of Fluorine Chemistry, 132(8), 541-547 (2011)
The13C NMR, UV and IR spectra of 2-fluoropyridine methyl derivatives.
Puszko A and Ciurla H.
Chemistry of Heterocyclic Compounds, 35(6), 677-687 (1999)
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