57903
碘甲基三甲基硅烷
≥99.0% (GC)
别名:
(三甲基硅)甲基碘
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关于此项目
线性分子式:
(CH3)3SiCH2I
化学文摘社编号:
分子量:
214.12
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-123-6
Beilstein/REAXYS Number:
1731485
MDL number:
产品名称
碘甲基三甲基硅烷, ≥99.0% (GC)
InChI key
VZNYXGQMDSRJAL-UHFFFAOYSA-N
InChI
1S/C4H11ISi/c1-6(2,3)4-5/h4H2,1-3H3
SMILES string
C[Si](C)(C)CI
assay
≥99.0% (GC)
refractive index
n20/D 1.491 (lit.)
n20/D 1.491
bp
139-141 °C (lit.)
density
1.443 g/mL at 25 °C (lit.)
functional group
iodo
Quality Level
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Other Notes
制备 2-(三甲基甲硅烷基)乙基三苯基碘化膦的原料，用于合成烯丙基硅烷；还用于酰胺的 N-烷基化，这是 [2+3]-环加成反应序列制备不稳定叶立德的步骤。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
D. Seyferth et al.
The Journal of Organic Chemistry, 42, 3104-3104 (1977)
I. Fleming et al.
Synthesis, 446-446 (1979)
E. Vedejs et al.
The Journal of Organic Chemistry, 48, 4773-4773 (1983)
E. Vedejs et al.
The Journal of Organic Chemistry, 50, 2170-2170 (1985)
Aleksandra Sadowska et al.
Frontiers in pharmacology, 11, 952-952 (2020-07-28)
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