592498
衣康酸二甲酯
99%
别名:
2-(Methylene)butanedioic dimethyl ester
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关于此项目
线性分子式:
CH3O2CCH2C(=CH2)CO2CH3
化学文摘社编号:
分子量:
158.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-519-6
Beilstein/REAXYS Number:
386674
MDL number:
产品名称
衣康酸二甲酯, 99%
InChI key
ZWWQRMFIZFPUAA-UHFFFAOYSA-N
InChI
1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3
SMILES string
COC(=O)CC(=C)C(=O)OC
assay
99%
form
solid
bp
208 °C (lit.)
mp
37-41 °C (lit.)
density
1.124 g/mL at 25 °C (lit.)
functional group
ester
Quality Level
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Application
衣康酸二甲酯可用于铑催化的(S)-二甲基-2-甲基琥珀酸酯 和(R)-甲基琥珀酸二甲酯的不对称氢化反应。
General description
衣康酸二甲酯可以通过衣康酸的酯化反应进行合成。
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2 - Skin Sens. 1B
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
212.0 °F - closed cup
flash_point_c
100 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
?Modification of poly(propylene) through grafting with dimethyl
itaconate in solution?
itaconate in solution?
Yazdani-Pedram M, et al.
Macromolecular Chemistry and Physics, 199(11), 2495- 2500 (1998)
"Catalytic asymmetric hydrogenation of dimethyl itaconate with trans-chelating chiral diphosphine ligands TRAP-rhodium complexes"
Kuwano R, et al.
Tetrahedron Asymmetry, 6(10), 2521- 2526 (1995)
?New ferrocenyl ligands with broad applications in asymmetric catalysis?
Lotz M, et al.
Angewandte Chemie (International Edition in English), 41(24), 4708-4711 (2002)
Yepin Zhao et al.
Advanced materials (Deerfield Beach, Fla.), 32(17), e1907769-e1907769 (2020-03-10)
Intrinsically, detrimental defects accumulating at the surface and grain boundaries limit both the performance and stability of perovskite solar cells. Small molecules and bulkier polymers with functional groups are utilized to passivate these ionic defects but usually suffer from volatility
Vittoria Chimisso et al.
Langmuir : the ACS journal of surfaces and colloids, 35(41), 13413-13420 (2019-10-05)
Poly(N-vinylcaprolactam-co-itaconate) (P(VCL-co-IADME) microgels were synthesized varying the molar ratio between VCL and IADME via free radical precipitation polymerization in the presence of quaternary ammonium surfactant. In order to determine the effect of the divalent metal ions on the structure and
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