63405
甲基丙二酸钾
≥99.0% (NT)
别名:
丙二酸单甲酯 钾盐, 丙二酸单甲酯钾盐
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线性分子式:
CH3OCOCH2COOK
化学文摘社编号:
分子量:
156.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
253-886-8
Beilstein/REAXYS Number:
3633585
MDL number:
产品名称
甲基丙二酸钾, ≥99.0% (NT)
InChI key
WWTULTKUWBKVGV-UHFFFAOYSA-M
InChI
1S/C4H6O4.K/c1-8-4(7)2-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
SMILES string
[K+].COC(=O)CC([O-])=O
assay
≥99.0% (NT)
functional group
ester
Quality Level
Application
Methyl potassium malonate can be used in the total synthesis of (±)-vincorine, an akuammiline alkaloid which can find applications in biology. It can also be used to synthesize a key keto proline ester intermediate to prepare acutumine.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
"The akuammiline alkaloids; origin and synthesis"
Eckermann R and Gaich C
Synthesis, 45(20), 2813- 2823 (2013)
?Classical carbonyl reactivity enables a short synthesis of the core structure of acutumine?
Moreau.JR and Sorensen.JE
Tetrahedron, 63(28), 6446-6453 (2007)
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