641979
对碘苯甲酸乙酯
97%
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关于此项目
经验公式（希尔记法）:
C9H9IO2
化学文摘社编号:
分子量:
276.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
InChI
1S/C9H9IO2/c1-2-12-9(11)7-3-5-8(10)6-4-7/h3-6H,2H2,1H3
SMILES string
CCOC(=O)c1ccc(I)cc1
InChI key
YCBJOQUNPLTBGG-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.5880 (lit.)
density
1.641 g/mL at 25 °C (lit.)
functional group
ester, iodo
Quality Level
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Application
Ethyl 4-iodobenzoate can be used in the synthesis of biphenyl derivatives via Negishi cross coupling with the intermediates of the type ArMg(tmp)·2LiCl (tmp = trimethylolpropane). It can also be used as a starting material in the synthesis of p-carbomethoxyphenylmagnesium bromide, a polyfunctional organometallic reagent that can be used as building block in the synthesis of complex target molecules.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
"Preparation and reactions of functionalized arylmagnesium reagents"
Jensen EA, et al.
Synthesis, 2002(04), 0565-0569 (2002)
"Direct Magnesiation of Polyfunctionalized Arenes and Heteroarenes Using (tmp) 2Mg? 2 LiCl"
Clososki.CG, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 46(40), 7681-7684 (2007)
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