648744
马来酰亚胺
97%
别名:
2-羟基-2-苯乙酰胺
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关于此项目
线性分子式:
C6H5CH(OH)CONH2
化学文摘社编号:
分子量:
151.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C8H9NO2/c9-8(11)7(10)6-4-2-1-3-5-6/h1-5,7,10H,(H2,9,11)
SMILES string
NC(=O)C(O)c1ccccc1
InChI key
MAGPZHKLEZXLNU-UHFFFAOYSA-N
assay
97%
form
solid
mp
133-137 °C (lit.)
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Pan-Fen Wang et al.
Protein engineering, design & selection : PEDS, 22(2), 103-110 (2008-12-17)
Mandelamide hydrolase (MAH), a member of the amidase signature family, catalyzes the hydrolysis of mandelamide to mandelate and ammonia. X-ray structures of several members of this family, but not that of MAH, have been reported. These reveal nearly superimposable conformations
Y Chiang et al.
Journal of the American Chemical Society, 125(1), 187-194 (2003-01-08)
Flash photolysis of diazophenylacetamide in aqueous solution produced phenylcarbamoylcarbene, whose hydration generated a transient species that was identified as the enol isomer of mandelamide. This assignment is based on product identification and the shape of the rate profile for decay
Gonzalo Blay et al.
Organic letters, 8(7), 1287-1290 (2006-03-28)
[reaction: see text] A strategy based on the control of the electron-donating capabilities of the coordinating groups of the ligand has been applied in the catalytic asymmetric addition of organometallic reagents to ketoesters. Mandelamides having deprotonated alcohol and carboxyamido groups
Biank T Gonçalves et al.
Magnetic resonance in chemistry : MRC, 46(5), 418-426 (2008-03-11)
Interesting anisotropic effects were observed for phenylglyoxamides and their respective mandelamides. Such effects were observed in experimental (1)H and (13)C NMR (in CDCl(3), CD(3)OD, and DMSO-d(6) solvents) and in some cases with good correlation to theoretical (1)H and (13)C NMR
Clemens Lamberth et al.
Pest management science, 62(5), 446-451 (2006-03-22)
Novel types of anti-oomycetic compounds have been designed and prepared. The synthetic approach to these mandelamides is outlined. Biological data demonstrate their high efficacy against important plant diseases such as tomato and potato late blight (Phytophthora infestans De Bary) and
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