产品名称
4,5-二溴-2-糠酸, 97%
InChI
1S/C5H2Br2O3/c6-2-1-3(5(8)9)10-4(2)7/h1H,(H,8,9)
SMILES string
OC(=O)c1cc(Br)c(Br)o1
InChI key
BHUVICYZDBUMIU-UHFFFAOYSA-N
assay
97%
form
solid
mp
169-173 °C
functional group
bromo
carboxylic acid
Quality Level
Application
用于研究呋喃环体系与悬垂烯丙酰胺之间的分子内 Diels-Alder 反应中卤取代呋喃基的影响。与氯代或无取代呋喃相比，C-5 溴取代可以提高环加成作用的产量。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Albert Padwa et al.
The Journal of organic chemistry, 71(15), 5432-5439 (2006-07-15)
Intramolecular Diels-Alder reactions involving a series of N-alkenyl-substituted furanyl amides were investigated. Stable functionalized oxanorbornenes were formed in high yield upon heating at 80-110 degrees C. The cycloaddition reactions include several bromo-substituted furanyl amides, and these systems were found to
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