661384
2-碘酰基苯甲酸
contains stabilizer, 45 wt. % (IBX)
别名:
2-碘酰苯甲酸, SIBX
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关于此项目
经验公式（希尔记法）:
C7H5IO4
化学文摘社编号:
分子量:
280.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
2-碘酰基苯甲酸, contains stabilizer, 45 wt. % (IBX)
InChI
1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)
SMILES string
OI1(=O)OC(=O)c2ccccc12
InChI key
CQMJEZQEVXQEJB-UHFFFAOYSA-N
form
solid
contains
stabilizer
reaction suitability
reagent type: oxidant
concentration
45 wt. % (IBX)
functional group
iodo
Quality Level
Application
是 IBX 的稳定形态 (SIBX)，不具有 IBX 的任何易爆性，同时保持了出色的反应性和选择性。
用于在 DMSO 存在的条件下将芴甲氧羰基保护的氨基醇氧化为相应的氨基醛的试剂。
Other Notes
本品在苯甲酸和间苯二甲酸中稳定。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3
target_organs
Lungs, Respiratory system
supp_hazards
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Aurélie Ozanne et al.
Organic letters, 5(16), 2903-2906 (2003-08-02)
[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use
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Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)
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Stefanie Deike et al.
Bioorganic chemistry, 101, 104012-104012 (2020-07-20)
Aggregation of amyloid peptides results in severe neurodegenerative diseases. While the fibril structures of Aβ40 and Aβ42 have been described recently, resolution of the aggregation pathway and evaluation of potent inhibitors still remains elusive, in particular in view of the
Synthetic Communications, 37, 3493-3493 (2007)
F Clemente et al.
Bioorganic chemistry, 98, 103740-103740 (2020-03-23)
The enzyme glucocerebrosidase (GCase) has become an important therapeutic target due to its involvement in pathological disorders consequent to enzyme deficiency, such as the lysosomal storage Gaucher disease (GD) and the neurological Parkinson disease (PD). Pharmacological chaperones (PCs) are small
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