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70956

Sigma-Aldrich

1-丁基-3-甲基咪唑六氟磷酸盐

≥97.0% (HPLC)

别名:
BMIMPF6
Empirical Formula (Hill Notation):
C8H15F6N2P
CAS号:
分子量:
284.18
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

200

测定

≥97.0% (HPLC)

折射率

n20/D 1.411 (lit.)

密度

1.38 g/mL at 20 °C (lit.)

SMILES string

F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

InChI key

IXQYBUDWDLYNMA-UHFFFAOYSA-N

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一般描述

1-丁基-3-甲基咪唑六氟磷酸盐是一种基于咪唑的疏水性室温离子液体 (RTIL)。 可由 1-甲基咪唑与氯丁烷反应制得。气态氢氟碳化合物 (HFCs) 如氟甲烷、氟乙烷和 1,1,2,2-四氟乙烷可溶于 BMIMPF 6

应用

1-丁基-3-甲基咪唑六氟磷酸盐是一种在许多环境友好反应中使用的离子液体。

它也可以作为反应的介质,例如:
  • 二烯和烯炔底物在新型可回收钌卡宾配合物存在下的关环复分解反应。
  • 乙酰丙酮镍 (II) 催化芳香醛氧化为相应的的酸,氧化剂为双氧水。
  • 脂肪酶催化烯丙醇的对映选择性酰化反应。
  • 用四烯丙基锡烷对醛进行烯丙基化,生成高烯丙基醇。

包装

5, 50, 250 g in glass bottle

象形图

Exclamation mark

警示用语:

Warning

危险声明

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

分析证书

原产地证书 (CofO)

Ionic liquids: a convenient solvent for environmentally friendly allylation reactions with tetraallylstannane.
Gordon C.
Chemical Communications (Cambridge, England), (15), 1431-1432 (1999)
Kamrul Hasan et al.
Scientific reports, 5, 12325-12325 (2015-07-17)
The synthesis, characterization and evaluation in solid-state devices of a series of 8 cationic iridium complexes bearing different numbers of methoxy groups on the cyclometallating ligands are reported. The optoelectronic characterization showed a dramatic red shift in the absorption and...
Diffusivities of gases in room-temperature ionic liquids: data and correlations obtained using a lag-time technique.
Morgan D, et al.
Industrial & Engineering Chemistry Research, 44(13), 4815-4823 (2005)
Carlos Adelantado et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 35(9), 1755-1766 (2018-07-12)
A simple and rapid microextraction procedure is reported on the use of ionic liquid in combination with magnetic nanocellulose hybrid nanoparticles. The procedure is ultrasound-assisted and applicable to selective preconcentration of neonicotinoid insecticides from milk samples, prior to being analysed...
C.M. Gordon et al.
Chemical Communications (Cambridge, England), 1431-1431 (1999)

实验方案

Enzymatic Reactions in Ionic Liquids

One of the most popular lipase for synthetic use is the Candida antarctica lipase (CALB). CALB catalyzes the enantioselective acylation of 1-phenylethylamine with 4-pentenoic acid

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