70956
1-丁基-3-甲基咪唑六氟磷酸盐
≥97.0% (HPLC)
别名:
BMIMPF6
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关于此项目
经验公式（希尔记法）:
C8H15F6N2P
化学文摘社编号:
分子量:
284.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
1-丁基-3-甲基咪唑六氟磷酸盐, ≥97.0% (HPLC)
InChI
1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
InChI key
IXQYBUDWDLYNMA-UHFFFAOYSA-N
assay
≥97.0% (HPLC)
form
liquid
Quality Level
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
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refractive index
n20/D 1.411 (lit.)
density
1.38 g/mL at 20 °C (lit.)
greener alternative category
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Application
1-丁基-3-甲基咪唑六氟磷酸盐是一种在许多环境友好反应中使用的离子液体。
它也可以作为反应的介质，例如：
它也可以作为反应的介质，例如：
- 二烯和烯炔底物在新型可回收钌卡宾配合物存在下的关环复分解反应。
- 乙酰丙酮镍 (II) 催化芳香醛氧化为相应的的酸，氧化剂为双氧水。
- 脂肪酶催化烯丙醇的对映选择性酰化反应。
- 用四烯丙基锡烷对醛进行烯丙基化，生成高烯丙基醇。
General description
BMIMPF6被用作各种合成和催化转化的高效反应介质。
1-丁基-3-甲基咪唑六氟磷酸是一种咪唑基、疏水、室温离子液体(RTIL)。它可以通过1-甲基咪唑与氯丁烷的反应来制备。气态氢氟碳化合物(HFC)，如氟甲烷、氟乙烷和1,1,2,2-四氟乙烷可溶于BMIMPF6。
1-丁基-3-甲基咪唑六氟磷酸是一种咪唑基、疏水、室温离子液体(RTIL)。它可以通过1-甲基咪唑与氯丁烷的反应来制备。气态氢氟碳化合物(HFC)，如氟甲烷、氟乙烷和1,1,2,2-四氟乙烷可溶于BMIMPF6。
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Ionic liquids: a convenient solvent for environmentally friendly allylation reactions with tetraallylstannane.
Gordon C.
Chemical Communications (Cambridge, England), (15), 1431-1432 (1999)
1-Butyl-3-methylimidazolium Hexafluorophosphate ([Bmim] PF6)
Yao Q
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Oxidation of aromatic aldehydes in the ionic liquid [bmim] PF6.
Howarth J.
Tetrahedron Letters, 41(34), 6627-6629 (2000)
Gaseous absorption of fluoromethane, fluoroethane, and 1, 1, 2, 2-tetrafluoroethane in 1-butyl-3-methylimidazolium hexafluorophosphate.
Shiflett MB and Yokozeki A.
Industrial & Engineering Chemistry Research, 45(18), 6375-6382 (2006)
Gulcin Bolat et al.
Sensors (Basel, Switzerland), 18(3) (2018-03-08)
Malathion (MLT) is an organophosphorous type pesticide and having seriously high toxicity and electrochemical platforms for rapid, simple, inexpensive and sensitive determination of pesticides is still a special concern. This paper describes a simple preparation of a composite film consisting
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