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Merck
CN

743003

Sigma-Aldrich

2-过氧化丁酮

technical

别名:

甲基乙基酮过氧化物, 过氧化甲乙酮

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关于此项目

线性分子式:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
化学文摘社编号:
分子量:
210.22
Beilstein:
1759757
MDL编号:
UNSPSC代码:
12352120
PubChem化学物质编号:
NACRES:
NA.22
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等级

technical

表单

liquid

包含

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

反应适用性

reagent type: oxidant

折射率

n20/D 1.432

密度

1.053 g/mL at 20 °C (lit.)

官能团

hydroperoxide
peroxide

储存温度

2-8°C

SMILES字符串

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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应用

反应物用于:
  • 过氧化甲乙酮绝热失控反应的研究
  • 磨料溶出方波伏安法测定考古玻璃中的金属离子
  • 过氧化氢和过氧化氢清除物质的光子发射成像
  • 亚磷酰胺法合成寡核苷酸
  • 核苷亚磷酸酯氧化成磷酸盐
  • 人血浆谷胱甘肽过氧化物酶作为氢过氧化物酶还原催化剂的比较

乙醇-水体系中固定化血红蛋白直接电化学催化的分析物

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

闪点(°F)

132.8 °F - closed cup

闪点(°C)

56 °C - closed cup

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jo-Ming Tseng et al.
Journal of hazardous materials, 142(3), 765-770 (2006-08-15)
Methyl ethyl ketone peroxide (MEKPO) is a typical organic peroxide with thermally unstable nature that has been broadly employed in the manufacturing process of acrylic resins, as a hardening agent for fiberglass-reinforced plastics, and as a curing agent for unsaturated
F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide.
A Prez-Martnez et al.
European journal of pediatrics, 156(12), 976-977 (1998-02-07)
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac

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