743003
2-过氧化丁酮
technical
别名:
甲基乙基酮过氧化物, 过氧化甲乙酮
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关于此项目
线性分子式:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
化学文摘社编号:
分子量:
210.22
UNSPSC Code:
12352120
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1759757
Form:
liquid
产品名称
2-过氧化丁酮, technical
InChI
1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3
SMILES string
CCC(C)(OO)OOC(C)(CC)OO
InChI key
WFUGQJXVXHBTEM-UHFFFAOYSA-N
grade
technical
form
liquid
contains
2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer
reaction suitability
reagent type: oxidant
refractive index
n20/D 1.432
density
1.053 g/mL at 20 °C (lit.)
functional group
hydroperoxide
peroxide
storage temp.
2-8°C
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Application
反应物用于：
乙醇-水体系中固定化血红蛋白直接电化学催化的分析物
- 过氧化甲乙酮绝热失控反应的研究
- 磨料溶出方波伏安法测定考古玻璃中的金属离子
- 过氧化氢和过氧化氢清除物质的光子发射成像
- 亚磷酰胺法合成寡核苷酸
- 核苷亚磷酸酯氧化成磷酸盐
- 人血浆谷胱甘肽过氧化物酶作为氢过氧化物酶还原催化剂的比较
乙醇-水体系中固定化血红蛋白直接电化学催化的分析物
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 1
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
法规信息
危险化学品
此项目有
Allergic contact dermatitis due to methyl ethyl ketone peroxide, cobalt naphthenate and acrylates in the manufacture of fibreglass-reinforced plastics.
Keiko Minamoto et al.
Contact dermatitis, 46(1), 58-59 (2002-03-29)
M V S Subbalaxmi et al.
The National medical journal of India, 23(3), 150-151 (2010-10-19)
Methyl ethyl ketone peroxide, commonly used in the lamination industry, is a highly inflammable substance. Ingestion of methyl ethyl ketone peroxide is associated with a high morbidity and mortality. It can cause injury to the gastrointestinal tract on ingestion, leading
N Bates et al.
Pediatrics, 108(2), 473-476 (2001-08-03)
A 6-year-old boy developed respiratory distress, metabolic acidosis, severe esophageal and gastric burns, and a coagulopathy after ingestion of an unknown volume of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. He was discharged from the pediatric intensive care unit
Yan-Fu Lin et al.
Journal of hazardous materials, 153(3), 1071-1077 (2007-11-09)
Runaway reactions by methyl ethyl ketone peroxide (MEKPO) are an important issue in Asia, due to its unstable structure and extensive heat release during upset situations. This study employed differential scanning calorimetry (DSC) to draw the experimental data for MEKPO
C C G van Enckevort et al.
Clinical toxicology (Philadelphia, Pa.), 46(1), 74-78 (2008-01-02)
The plastic hardener methyl ethyl ketone peroxide (MEKP) is an unstable peroxide that releases free oxygen radicals. Ingestion of this compound induces widespread liver necrosis that is often fatal, extensive ulceration with subsequent scarring, and stenosis of the proximal digestive
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