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Merck
CN

75059

1-丁基-3-甲基咪唑硫酸辛酯

≥95.0% (HPLC)

别名:

BMIM OSU

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关于此项目

经验公式(希尔记法):
C16H32N2O4S
化学文摘社编号:
分子量:
348.50
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

1-丁基-3-甲基咪唑硫酸辛酯, ≥95.0% (HPLC)

InChI key

KIDIBVPFLKLKAH-UHFFFAOYSA-M

SMILES string

CCCCn1cc[n+](C)c1.CCCCCCCCOS([O-])(=O)=O

InChI

1S/C8H15N2.C8H18O4S/c1-3-4-5-10-7-6-9(2)8-10;1-2-3-4-5-6-7-8-12-13(9,10)11/h6-8H,3-5H2,1-2H3;2-8H2,1H3,(H,9,10,11)/q+1;/p-1

assay

≥95.0% (HPLC)

impurities

≤1.0% water

Quality Level

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Application

在铑催化剂存在下 1-辛烯加氢甲酰化形成壬醛过程中,1-丁基-3-甲基咪唑硫酸辛酯可用作溶剂。

General description

1-丁基-3-甲基咪唑硫酸辛酯是无卤素的离子液体。当临界胶束浓度(CMC)高于 0.031M 时,它可作为表面活性剂。

Other Notes

在酶催化合成反应中可增加 β-半乳糖苷酶的产率和稳定性

Physical form

非卤代离子液体

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Solubility and excess molar properties of 1, 3-dimethylimidazolium methylsulfate, or 1-butyl-3-methylimidazolium methylsulfate, or 1-butyl-3-methylimidazolium octylsulfate ionic liquids with n-alkanes and alcohols: analysis in terms of the PFP and FBT models 1.
Domanska, U., A. Pobudkowska, and A. Wisniewska
Journal of Solution Chemistry, 35.3, 331-334 (2006)
1-n-Butyl-3-methylimidazolium ([bmim]) octylsulfate-an even 'greener'ionic liquid.
Wasserscheid P, et al.
Green Chemistry, 4(4), 400-404 (2002)
Micellar transitions in the aqueous solutions of a surfactant-like ionic liquid: 1-butyl-3-methylimidazolium octylsulfate
Singh, Tejwant, et al.
Physical Chemistry Chemical Physics, 12.37, 11728-11735 (2010)
Hakimu Nsubuga et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1012-1013, 1-7 (2016-01-23)
A simple and parallel electromembrane extraction (pEME) method was developed and used to investigate trace perchlorate ion contamination in seafood. In this method, three different EME units were arranged simultaneously and connected parallel to a single DC power supply. In
Volumetric properties of binary mixtures of ionic liquid 1-butyl-3-methylimidazolium octylsulfate with water or propanol in the temperature range of 278.15 K to 328.15 K.
Orchilles, A. Vicent, et al.
The Journal of Chemical Thermodynamics, 38.9, 1124-1129 (2006)

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