A76206
( S )-(+)-2-氨基-1-丙醇
98%
别名:
L-丙氨醇
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线性分子式:
CH3CH(NH2)CH2OH
化学文摘社编号:
分子量:
75.11
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-388-7
Beilstein/REAXYS Number:
1718865
MDL number:
产品名称
( S )-(+)-2-氨基-1-丙醇, 98%
InChI key
BKMMTJMQCTUHRP-VKHMYHEASA-N
InChI
1S/C3H9NO/c1-3(4)2-5/h3,5H,2,4H2,1H3/t3-/m0/s1
SMILES string
C[C@H](N)CO
assay
98%
form
liquid
optical activity
[α]20/D +18°, neat
optical purity
ee: 97% (GLC)
refractive index
n20/D 1.4498 (lit.)
bp
72-73 °C/11 mmHg (lit.)
density
0.965 g/mL at 25 °C (lit.)
Quality Level
Application
可与芳基腈类反应生成噁唑啉类用以参与钯催化的烯丙基取代反应。
（S）-（+）-2-氨基-1-丙醇可用于通过与羰基化合物缩合制备不对称三齿席夫碱配体。它也可以用作制备 4-N-[（2-羟基-1-（S）-甲基）乙基氨基] -2-亚甲基-4-（S）-苯基-丁酸叔丁酯的手性辅助剂。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Tetrahedron Asymmetry, 4, 1785-1785 (1993)
Towards the Determination of the Absolute Configuration of Complex Molecular Systems: Matrix Isolation Vibrational Circular Dichroism Study of (R)-2-Amino-1-propanol.
Tarczay G, et al.
Angewandte Chemie (International Edition in English), 45(11), 1775-1777 (2006)
Chiral oxidovanadium (V) complexes with tridentate Schiff bases derived from S (+)-2-amino-1-propanol: Synthesis, structure, characterization and catalytic activity.
Romanowski G and Lis T.
Inorgorganica Chimica Acta, 394, 627-634 (2013)
Tetrahedron Letters, 34, 3149-3149 (1993)
Tetrahedron Letters, 34, 7725-7725 (1993)
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