B57400
4-溴苯甲醛
ReagentPlus®, 99%
别名:
1-溴-4-甲酰苯, 4-溴苯甲醛, 4-甲酰基-1-溴苯, 4-甲酰基苯基溴, 4-甲酰溴苯, 对溴苯甲醛, 对甲酰基溴苯
质量水平
产品线
ReagentPlus®
方案
99%
表单
crystals
mp
55-58 °C (lit.)
SMILES字符串
[H]C(=O)c1ccc(Br)cc1
InChI
1S/C7H5BrO/c8-7-3-1-6(5-9)2-4-7/h1-5H
InChI key
ZRYZBQLXDKPBDU-UHFFFAOYSA-N
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应用
4-溴苯甲醛可用作反应剂：
- 在三苯基膦催化剂存在下，与端炔酸酯类反应合成乙烯酯类。
- 与苯乙烯通过钯催化的Mizoroki-Heck交联反应合成芳基化烯烃。
- 与甲酰基苯硼酸类通过Suzuki-Wittig反应合成二甲基二苯基二丙烯酸酯类。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
228.2 °F - closed cup
闪点(°C)
109 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Gary A Molander et al.
The Journal of organic chemistry, 71(26), 9681-9686 (2006-12-16)
We have previously reported that the palladium-catalyzed cross-coupling reaction of potassium vinyltrifluoroborate with aryl electrophiles proceeds with good yields. Herein, we describe recent progress in optimizing the reaction, as well as outlining the scope and limitations of the reaction. The
Tetrahedron Letters, 48, 539-539 (2007)
Timo Rhauderwiek et al.
Chemical science, 9(24), 5467-5478 (2018-07-17)
The Ni-metallated porphyrin-based tetraphosphonic acid (Ni-tetra(4-phosphonophenyl)porphyrin, Ni-H8TPPP) was used for the synthesis of highly porous metal phosphonates containing the tetravalent cations Zr4+ and Hf4+. The compounds were thoroughly characterized regarding their sorption properties towards N2 and H2O as well as
Gugu Kubheka et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 191, 357-364 (2017-10-22)
The optical limiting (OL) properties of 3,5-dipyrenylvinyleneBODIPY dyes that contain both electron withdrawing and donating moieties have been investigated by using the z-scan technique at 532nm in the nanosecond pulse range. The extension of the π-conjugation at the 3,5-positions with
Ved Vati Singh et al.
Dalton transactions (Cambridge, England : 2003), 44(2), 725-732 (2014-11-20)
The metastable tetragonal Cu2Se phase as nanoflakes has been synthesized for the first time by treating CuCl2 taken in a mixture (1:1) of 1-octadecene and oleylamine with H2N-(CH2)3-SePh dissolved in 1-octadecene. Powder X-ray diffraction (PXRD), HRTEM, SEM-EDX and XPS have
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Effective in key synthesis reactions like Knoevenagel condensation, thalidomide synthesis, and Suzuki coupling for sustainable chemical transformations.
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