B73201
1-溴-2-萘酚
97%
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线性分子式:
BrC10H6OH
化学文摘社编号:
分子量:
223.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-363-1
MDL number:
Assay:
97%
Form:
powder
InChI
1S/C10H7BrO/c11-10-8-4-2-1-3-7(8)5-6-9(10)12/h1-6,12H
InChI key
FQJZPYXGPYJJIH-UHFFFAOYSA-N
SMILES string
Oc1ccc2ccccc2c1Br
assay
97%
form
powder
mp
78-81 °C (lit.)
Quality Level
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Chaoren Shen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(54), 13369-13378 (2017-06-27)
The palladium-catalyzed chemoselective carbonylation of bromoaryl triflates is reported. The selective C-Br bond versus C-OTf (OTf=triflate) bond functionalization can be remarkably tuned by the combination of the ligand [4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (Xantphos) vs. 1,1'-bis(diphenylphosphino)ferrocene (DPPF)] and the solvent (toluene vs. DMSO). The
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