Merck
CN
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文件

安全信息

B83207

Sigma-Aldrich

5-溴戊腈

98%

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线性分子式:
Br(CH2)4CN
CAS号:
5414-21-1
分子量:
162.03
Beilstein:
1742080
EC 号:
226-505-8
MDL编号:
MFCD00001976
PubChem化学物质编号:
24891939
NACRES:
NA.22

检测方案

98%

形式

liquid

折射率

n20/D 1.478 (lit.)

密度

1.388 g/mL at 25 °C (lit.)

SMILES string

BrCCCCC#N

InChI

1S/C5H8BrN/c6-4-2-1-3-5-7/h1-4H2

InChI key

NWWWGAKVHCSAEU-UHFFFAOYSA-N

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应用

5-Bromovaleronitrile can be used as a reactant to prepare:
  • A key intermediate benzyl(methyl)amino)pentanenitrile, which is used in the synthesis of N-methylcadaverine.
  • 1-cyanobutyl-3-alkylbenzimidazolium bromide salt by reacting with various N-alkylbenzimidazoles.
  • Tridecanenitrile by Ni-catalyzed cross-coupling reaction with dioctylzinc in the presence of tetraene and MgBr2.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319 - H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Nickel-catalyzed cross-coupling reaction of alkyl halides with organozinc and Grignard reagents with 1,3,8,10-tetraenes as additives.
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Angewandte Chemie (International ed. in English), 43(45), 6180-6182 (2004-11-19)
Kayla N Anderson et al.
Molecules (Basel, Switzerland), 23(5) (2018-05-23)
Alkaloids compose a large class of natural products, and mono-methylated polyamines are a common intermediate in their biosynthesis. In order to evaluate the role of selectively methylated natural products, synthetic strategies are needed to prepare them. Here, N-methylcadaverine is prepared
Nitrile functionalized silver (I) N-heterocyclic carbene complexes: DFT calculations and antitumor studies
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Transition Metal Chemistry, 43(4), 301-312 (2018)
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Dalton transactions (Cambridge, England : 2003), 47(4), 1233-1242 (2018-01-05)
Substituted amino-piperazine derivatives were synthesized and used as precursors for the preparation of a series of new organometallic Re(i) imine complexes with the general formula [(η
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Scientific reports, 6, 37631-37631 (2016-11-25)
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