C11081
四溴甲烷
ReagentPlus®, 99%
别名:
四溴化碳
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关于此项目
经验公式（希尔记法）:
CBr4
化学文摘社编号:
分子量:
331.63
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-189-6
Beilstein/REAXYS Number:
1732799
MDL number:
产品名称
四溴甲烷, ReagentPlus®, 99%
InChI key
HJUGFYREWKUQJT-UHFFFAOYSA-N
InChI
1S/CBr4/c2-1(3,4)5
SMILES string
BrC(Br)(Br)Br
vapor pressure
40 mmHg ( 96 °C)
product line
ReagentPlus®
assay
99%
form
crystals
bp
190 °C (lit.)
mp
88-90 °C (lit.)
Quality Level
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Application
四溴甲烷可用于以下用途：
- 作为转移剂用于甲基丙烯酸甲酯和 p -二乙烯基苯的共聚合，形成可溶的交联聚合物。
- 作为催化剂，在无金属条件下，由苯甲醇进行好氧光氧化合成芳香酯。
- 铁化合物催化下金刚烷及其衍生物的溴代反应。
General description
四溴甲烷可在有价化学品的合成中充当介质、催化剂和试剂。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
Aerobic oxidative esterification of benzyl alcohols with catalytic tetrabromomethane under visible light irradiation.
Nobuta T
Tetrahedron Letters, 53(39), 5306-5308 (2012)
Bromination of adamantane and its derivatives with tetrabromomethane catalyzed by iron compounds.
Khusnutdinov RI
Russ. J. Org. Chem., 51(2), 184-187 (2015)
Recent advances in the application of tetrabromomethane in organic synthesis
Kumar S, et al.
Inorganic chemistry frontiers, 8(15), 4288-4314 (2021)
Preparation of soluble microgel by the copolymerization of methylmethacrylate with p?divinylbenzene in the presence of tetrabromomethane.
Chen H
Journal of Polymer Science Part A: Polymer Chemistry, 22(9), 2123-2130 (1984)
A K Agarwal et al.
Toxicology letters, 17(1-2), 57-62 (1983-06-01)
The hepatotoxic and nephrotoxic effects of CBr4 were studied in male Sprague-Dawley rats following a single i.p. administration in a dose range of 25 to 125 microliter/kg to animals maintained for 15 days either on normal diet or a diet
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