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Merck
CN

C409

(1R,3S)-(+)-樟脑酸

99%

别名:

(+)-樟脑酸, (1R,3S)-1,2,2-三甲基-1,3-环戊烷二羧酸

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关于此项目

经验公式(希尔记法):
C10H16O4
化学文摘社编号:
分子量:
200.23
UNSPSC Code:
51113400
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-715-0
Beilstein/REAXYS Number:
2050204
MDL number:
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产品名称

(1R,3S)-(+)-樟脑酸, 99%

InChI key

LSPHULWDVZXLIL-LDWIPMOCSA-N

InChI

1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1

SMILES string

CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O

assay

99%

form

powder

optical activity

[α]20/D 46°, c = 1 in ethanol

mp

183-186 °C (lit.)

Quality Level

Application

(1R,3S)-(+)-樟脑酸可用于制备(1R,2S,3R,5S)-2,3-二苄基-1,8,8-三甲基-3-硫杂双环[3.2.1] 辛烷高氯酸盐。它与吡啶(py)或吡啶/甲醇(MeOH)中的硝酸铀酰反应形成新型铀酰-有机组合。

General description

樟脑酸是一种二酸,一般通过萜烯(+)-樟脑氧化制备。它可用作一些有机反应中的手性诱导剂。

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Preparation of optically active epoxides via sulfur ylides. Origin of the chiral induction.
Breau L and Durst T.
Tetrahedron Asymmetry, 2(5), 367-370 (1991)
Synthesis, characterization, and water-degradation of biorenewable polyesters derived from natural camphoric acid
Nsengiyumva O and Miller SA
Green Chemistry, 21(5), 973-978 (2019)
Solvothermal Synthesis and Crystal Structure of Uranyl Complexes with 1, 1-Cyclobutanedicarboxylic and (1R, 3S)-(+)-Camphoric Acids-Novel Chiral Uranyl-Organic Frameworks.
Thuery P.
European Journal of Inorganic Chemistry, 2006(18), 3646-3651 (2006)
Spontaneous resolution to absolute chiral induction: pseudo-kagome type homochiral Zn (II)/Co (II) coordination polymers with achiral precursors
Bisht KK and Suresh E
Journal of the American Chemical Society, 135(42), 15690-15693 (2013)
Carine Robert et al.
Nature communications, 2, 586-586 (2011-12-14)
The vast majority of commodity materials are obtained from petrochemical feedstocks. These resources will plausibly be depleted within the next 100 years, and the peak in global oil production is estimated to occur within the next few decades. In this

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