Merck
CN
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文件

C8136

Sigma-Aldrich

氯冉酸

≥98%

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别名:
2,5-二氯-3,6-二羟基对苯醌, NSC 6108, NSC 97383
经验公式（希尔记法）:
C6H2Cl2O4
CAS号:
87-88-7
分子量:
208.98
Beilstein:
1875040
EC 号:
201-780-7
MDL编号:
MFCD00001596
PubChem化学物质编号:
57654044
NACRES:
NA.22

检测方案

≥98%

形式

powder

mp

≥300 °C (lit.)

SMILES string

OC1=C(Cl)C(=O)C(O)=C(Cl)C1=O

InChI

1S/C6H2Cl2O4/c7-1-3(9)5(11)2(8)6(12)4(1)10/h9,12H

InChI key

IPPWILKGXFOXHO-UHFFFAOYSA-N

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应用

作为以下反应的反应物：
  • 在研究尺寸控制的反应中充当质子供体
  • 合成二甲基联吡啶配合物
  • 合成（壬基苯并咪唑基甲基）苯用于制备中性的垂直转子形二铼金属环
  • 与酒石酸美托洛尔的电荷转移反应
  • 与有机碱的盐形成
  • 合成具有抗癌活性的锇金属矩形

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319 - H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Elmorsy Khaled
Talanta, 75(5), 1167-1174 (2008-07-01)
A simple, rapid and accurate method for the spectrophotometric determination of terfenadine has been developed. The proposed method based on the charge-transfer reactions of terfenadine, as n-electron donor, with 7,7,8,8-tetracyanoquinodimethane (TCNQ), tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) or 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone (chloranilic acid, p-CLA)
Kil Sik Min et al.
Journal of the American Chemical Society, 129(8), 2360-2368 (2007-02-03)
Dinuclear [(TPyA)MII(CA2-)MII(TPyA)]2+ [TPyA=tris(2-pyridylmethyl)amine; CA2-=chloranilate dianion; M=Co (1(2+)), Fe (2(2+))] complexes have been prepared by the reaction of M(BF4)(2).6H2O, TPyA, H2CA, and triethylamine in MeOH solution. Their reduced forms [(TPyA)MII(CA*3-)MII(TPyA)]+ [M=Co(1+), Fe (2+)] have been synthesized by using cobaltocene, and oxidized
Nikola Biliškov et al.
The journal of physical chemistry. A, 115(14), 3154-3166 (2011-03-25)
Hydrogen bonding and proton transfer in the solid state are studied on the crystals of isostructural anhydrous potassium and rubidium complex chloranilates by variable-temperature single crystal X-ray diffraction, solid state (1)H NMR and IR spectroscopies, and periodic DFT calculations of
Cristina I C Silvestre et al.
Talanta, 79(4), 1177-1180 (2009-07-21)
A fully automated methodology was developed for the determination of the thyroid hormones levothyroxine (T4) and liothyronine (T3). The proposed method exploits the formation of highly coloured charge-transfer (CT) complexes between these compounds, acting as electron donors, and pi-acceptors such
Dong Guo et al.
Inorganic chemistry, 46(8), 3257-3274 (2007-03-21)
The synthesis, physical, and spectroscopic properties of a series of metal complexes bridged by the redox-active chloranilate ligand are described. Compounds containing the (CAcat,cat)4- ligand, where (CAcat,cat)4- represents the fully reduced aromatic form of chloranilate, have been prepared by two
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