D27004
N,N′-二苯基乙二胺
98%
别名:
1,2-双苯胺基乙烷, N,N′-乙烯基二苯胺, 醛的 Wanzlick 试剂
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关于此项目
线性分子式:
C6H5NHCH2CH2NHC6H5
化学文摘社编号:
分子量:
212.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-765-6
Beilstein/REAXYS Number:
646740
MDL number:
Assay:
98%
Form:
powder
InChI key
NOUUUQMKVOUUNR-UHFFFAOYSA-N
InChI
1S/C14H16N2/c1-3-7-13(8-4-1)15-11-12-16-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2
SMILES string
C(CNc1ccccc1)Nc2ccccc2
assay
98%
form
powder
Quality Level
mp
65-67 °C (lit.)
Application
N,N′-Diphenylethylenediamine can be used:
- To prepare nickel(II) chelates to study their chemical reactivities.
- To prepare N-heterocyclic carbene (NHC) adducts by reacting with substituted benzaldehydes.
- As a starting material to prepare substituted cyclic poly(methyl methacrylate)s.
Other Notes
残留物主要为 1,4-二苯基哌嗪
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
J. Korean Chem. Soc., 36, 872-872 (1992)
Takashi Yoshitake et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 807(2), 177-183 (2004-06-19)
A highly selective and sensitive column liquid chromatographic method for fluorescence determination of serotonin (5-HT), dopamine (DA), noradrenaline (NA) and their related metabolites 5-hydroxyindole-3-acetic acid (5-HIAA) and 3,4-dihydroxyphenylacetic acid (DOPAC) following derivatization with benzylamine and 1,2-diphenylethylenediamine (DPE) is described. The
A Mitsui et al.
Journal of chromatography, 344, 61-70 (1985-11-08)
A simple, rapid and highly sensitive method for the determination of catecholamines (norepinephrine, epinephrine and dopamine) in human plasma is described which employs high-performance liquid chromatography with fluorescence detection. After cation-exchange chromatography on a Toyopak SP cartridge, the catecholamines and
Yangzhou Li et al.
Organic & biomolecular chemistry, 3(14), 2513-2518 (2005-07-07)
Polymer-supported chiral ligands 9 and 17 were prepared based on Noyori's (1S,2S)- or (1R,2R)-N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine. The combination with [RuCl2(p-cymene)]2 has been shown to exhibit high activities and enantioselectivities for heterogeneous asymmetric transfer hydrogenation of aromatic ketones (19a-c) with formic acid-triethylamine azeotrope
M Noji et al.
Chemico-biological interactions, 51(1), 37-48 (1984-09-01)
A series of Pt(II) complexes containing 1,2-diphenylethylenediamine (stien) isomers were synthesized and tested for their antitumor activity against leukemia L1210. Among the Pt(II) complexes examined water-soluble Pt(II) complexes with sulfate, nitrate and D-glucuronate ions as leaving groups exhibited relatively high
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