D27004
N,N′-二苯基乙二胺
98%
别名:
1,2-双苯胺基乙烷, N,N′-乙烯基二苯胺, 醛的 Wanzlick 试剂
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关于此项目
线性分子式:
C6H5NHCH2CH2NHC6H5
化学文摘社编号:
分子量:
212.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-765-6
Beilstein/REAXYS Number:
646740
MDL number:
产品名称
N,N′-二苯基乙二胺, 98%
InChI key
NOUUUQMKVOUUNR-UHFFFAOYSA-N
InChI
1S/C14H16N2/c1-3-7-13(8-4-1)15-11-12-16-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2
SMILES string
C(CNc1ccccc1)Nc2ccccc2
assay
98%
form
powder
mp
65-67 °C (lit.)
Quality Level
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Other Notes
残留物主要为 1,4-二苯基哌嗪
Application
N,N′-Diphenylethylenediamine can be used:
- To prepare nickel(II) chelates to study their chemical reactivities.
- To prepare N-heterocyclic carbene (NHC) adducts by reacting with substituted benzaldehydes.
- As a starting material to prepare substituted cyclic poly(methyl methacrylate)s.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
M Noji et al.
Chemico-biological interactions, 51(1), 37-48 (1984-09-01)
A series of Pt(II) complexes containing 1,2-diphenylethylenediamine (stien) isomers were synthesized and tested for their antitumor activity against leukemia L1210. Among the Pt(II) complexes examined water-soluble Pt(II) complexes with sulfate, nitrate and D-glucuronate ions as leaving groups exhibited relatively high
Yangzhou Li et al.
Organic & biomolecular chemistry, 3(14), 2513-2518 (2005-07-07)
Polymer-supported chiral ligands 9 and 17 were prepared based on Noyori's (1S,2S)- or (1R,2R)-N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine. The combination with [RuCl2(p-cymene)]2 has been shown to exhibit high activities and enantioselectivities for heterogeneous asymmetric transfer hydrogenation of aromatic ketones (19a-c) with formic acid-triethylamine azeotrope
A general and versatile approach to thermally generated N-heterocyclic carbenes
Nyce GW, et al.
Chemistry?A European Journal , 10(16), 4073-4079 (2004)
Yoshitane Imai et al.
Organic letters, 10(3), 469-471 (2008-01-11)
In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1'-binaphthyl-2,2'-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules: (1R,2R)-1, (1S,2S)-1, (R)-2, and (S)-2.
Determination of plasma catecholamines via condensation with diphenylethylenediamine: simplification of the procedure.
P Husek et al.
Journal of chromatography, 533, 166-170 (1990-11-30)
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